화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.43, No.28, 12705-12712, 2018
The investigation of Ag & LaCo0.6Ni0.4O3-delta composites as cathode contact material for intermediate temperature solid oxide fuel cells
The high interface resistance between cathodes and interconnects is a major cause for performance degradation of solid oxide fuel cells (SOFCs). Ag particles were mixed to LaCo0.6Ni0.4O3-delta (LCN) matrix which prevented the silver densification and demonstrated porosity microstructure. The composites with different Ag content were evaluated as cathode contact materials with SUS430 alloy as interconnects. The area specific resistance (ASR) of SUS430/10%Ag & LCN/SUS430 showed the optimal performance in which the ASR was 73 m Omega cm(2) after 50 h at 750 degrees C and showed stable property in 10 thermal cycles from 200 degrees C to 750 degrees C. The excellent performance of 10%Ag & LCN is attributed to the high conductivity of silver, the stable microstructure of LCN and its good interface adhesion with the interconnect alloy. With 10%Ag & LCN as cathode contact materials, the power density of a single cell reached 0.623 W/cm(2) at 750 degrees C and the average degradation is lower than 1% in 3 thermal cycles. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.