(100) Oriented niobium (Nb) crystals annealed in the vacuum conditions close to that used in mass production of 1.3 GHz superconducting radio frequency cavities for linear accelerators and treated in nitrogen at a partial pressure of 0.04 mbar at temperatures of 800 and 900 degrees C have been studied. The surfaces of the nitrogen-treated samples were investigated by means of various surface-sensitive techniques, including grazing-incidence X-ray diffraction, X-ray pho-toemission spectroscopy, and scanning electron microscopy with energy-dispersive X-ray spectroscopy in planar view and on cross-sections prepared by a focused ion beam. The appearance of a dense layer of epitaxial rectangular precipitates has been observed for the Niobium nitrided at 900 degrees C. Increased nitrogen concentration in the near-surface region was detected by glow-discharge optical-emission spectroscopy, focused ion-beam cross-sectional images and X-ray photoelectron spectroscopy. Crystalline phases of NbO and beta-Nb2N were identified by X-ray diffraction. This information was confirmed by X-ray photoelectron measurements, which in addition revealed the presence of Nb2O5, NbON, NbN, and NbNxOy components on the surface. These results establish the near-surface Nb phase composition after high-temperature nitrogen treatment, which is important for obtaining a better understanding of the improved RF cavity performance.