A series of tetrapolyesters were obtained by polymerizing phloretic acid, hydroquinone, p-hydroxybenzoic acid, or its derivatives, that is, vanillic acid or syringic acid, and dodecanedioic acid. Each monomer was polymerized in its acetylated form, except for the diacid to undergo polymerization by acidolysis. Initial polymerizations had shown that the use of phloretic acid resulted in better polymer properties than with p-coumaric acid. The predominantly renewable polymers were obtained by melt polymerization using a two-stage condensation process whereby antimony(III) oxide was applied as catalyst. Monomer conversions were typically close to 90%. H-1 and C-13 NMR, DSC, TGA, solution viscometry, and GPC were applied, as well as polarized microscopy to determine polymer microstructure and composition, transition temperatures, decomposition temperatures, intrinsic viscosities, and other molecular weight properties, and when applicable the liquid crystalline behavior of the polymers. All peaks, including end group peaks in the C-13 NMR spectra were assigned, the monomer sequence distribution was verified to be random, and a complete dyad analysis involving nine dyads and eight peaks was performed. By using p-hydroxybenzoic acid and its derivatives without any, one or two methoxy groups and varying the copolymer compositions, melting temperatures could be tuned between 106 and 181 degrees C. The tetrapolyesters, which included residues of p-hydroxybenzoic acid, formed nematic liquid crystals. (c) 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018, 56, 1498-1507