화학공학소재연구정보센터
Journal of Power Sources, Vol.391, 162-169, 2018
Highly activated porous carbon with 3D microspherical structure and hierarchical pores as greatly enhanced cathode material for highperformance supercapacitors
Highly activated porous carbon with attractive and promising electrochemical properties is employed as cathode material for high performance supercapacitors. The present paper proposes a novel activated porous carbon which is derived from zinc-based metal organic framworks as a source and template by carbonization at 825 degrees C and also further activation with KOH. The obtained activated porous carbon has uniform unique spherical morphology with an average size of 3-5 mu m and has a specific surface area up to 2314.9 m(2)g(-1). The activated porous carbon with superior mesoporous structure exhibits a high electrochemical performance and an excellent electrochemical stability in 6 M KOH solution. It provides a high specific capacitance and power density of 325 F g(-1) and 71.2 W kg(-1), respectively, at a current density of 1 A g(-1). Additionally, the activated porous carbon retains its specific capacitance with very slight decay rate of 1.21% after 150,000 cycles at an ultrahigh current density of 50 A g(-1). Hence, the present investigation demonstrates that the as-prepared activated porous carbon is a promising candidate as a low-cost and highly efficient electrode material for high-performance supercapacitors.