Efficient and selective photostimulated CO2-to-CO reduction by a photocatalytic system consisting of an iron-complex catalyst and a mesoporous graphitic carbon nitride (mpg-C3N4) redox photosensitizer is reported for the first time. Irradiation in the visible region (lambda >= 400 nm) of an CH3CN/triethanolamine (4:1, v/v) solution containing [Fe(qpy)(H2O)(2)](2+) (qpy = 2,2':6',2 '':6 '',2 ''-quaterpyridine) and mpg-C3N4 resulted in CO evolution with 97% selectivity, a turnover number of 155, and an apparent quantum yield of ca. 4.2%. This hybrid catalytic system, comprising only earth abundant elements, opens new perspectives for solar fuels production using CO2 as a renewable feedstock