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Journal of the Electrochemical Society, Vol.165, No.5, A1122-A1128, 2018
Influence of the Binder on Lithium Ion Battery Electrode Tortuosity and Performance
The electrochemical performance of porous graphite anodes in lithium ion battery applications is limited by the lithium ion concentration gradients in the liquid electrolyte, especially at high current densities and for thick coatings during battery charging. Beside the electrolyte transport parameters, the porosity and the tortuosity of the coating are key parameters that determine the electrode's suitability for high power applications. Here, we investigate the tortuosity of graphite anodes using two water as well as three n-methyl-2-pyrrolidone based binder systems by analysis of symmetric cell impedance measurements, demonstrating that tortuosities ranging from similar to 3-10 are obtained for graphite anodes of similar thickness (similar to 100 mu m), porosities (similar to 50%) and areal capacity (similar to 3.4 mAh/cm(2)). Furthermore, selected electrodes with tortuosities of 3.1, 4.3, and 10.2 were cycled in cells with reference electrode at charging C-rates from 0.1-20 1/h, illustrating the clear correlation between electrode tortuosity and its rate capability. (C) The Author(s) 2018. Published by ECS.