화학공학소재연구정보센터
Materials Chemistry and Physics, Vol.214, 143-153, 2018
Influence of Neodymium and gamma rays irradiation on structural electrical and magnetic properties of Co-Zn nanoferrites
Nanostructured Co1-xZn5NdyFe2-yO4 (0 <= x <= 1.0; y = 0.0 and 0.1) ferrites were synthesized through combustion route. All the compositions were irradiated with Co-60 gamma with total exposure dose 310 kGy at the dose rate 6.1kGy/h. The virgin and irradiated nanoparticles were characterized by the techniques; XRD, FFIR, SEM and EDAX. The DC electrical conductivity was measured in temperature range 300-800K. Magnetic parameters were measured with vibrating sample magnetometer (VSM) at 300K. Characterization studies reveal the structure, size, morphology and composition of the nanoferrites. The x-ray diffraction analysis revealed the cubic spinel ferrite structure. The characteristic feature of nanoferrites was confirmed by two prominent absorption bands v1 and v2 in the range 566-607 cm(-1) and 401-498cm(-1). The SEM micrographs evidenced almost spherical shaped agglomerated grainy structure of nanoferries. DC conductivity studies revealed that Curie temperature (T-c) decreased with increasing Zn2+ ion and Nd3+ ion substitution due to the weakening of A-B interaction. The observed enhancement of DC conductivity and magnetic parameters on gamma-irradiation attributed to the rearrangement of cations at A-site and B-site in the lattice. (C) 2018 Elsevier B.V. All rights reserved.