Journal of Polymer Science Part B: Polymer Physics, Vol.34, No.3, 395-399, 1996
The Counterion Distribution in Solutions of Rod-Shaped Polyelectrolytes (Reprinted from Journal-of-Polymer-Science, Vol 7, Pg 543-547)
For solutions containing rod-shaped polyelectrolytes and their counterions only, the Poisson-Boltzmann equation can be solved explicitly without the usual assumption of the Deybe-Huckel theory. At charge densities corresponding to half-neutralized polyacrylic acid a large proportion of monovalent counterions is located close to the polyion even in solutions as dilute as 1/800 base molar.