화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.65, 137-145, September, 2018
DOI10.1016/j.jiec.2018.04.022  Export Citation
Performance of EMIMFSI ionic liquid based gel polymer electrolyte in rechargeable lithium metal batteries
Liton Balo, Himani Gupta, Shishir Kumar Singh, Varun Kumar Singh, Shalu Kataria1, and Rajendra Kumar Singh†
  • Ionic Liquid and Solid State Ionics Lab, Department of Physics, Banaras Hindu University, Varansi 221005, India
  • 1Centre of Material Sciences, IIDS, University of Allahabad, Allahabad 211002, India
E-mail:
Flexible gel polymer electrolytes based on polymer polyethylene oxide, salt lithium bis(fluorosulfonyl) imide and ionic liquid 1-ethyl-3-methylimidazolium bis(fluorosulfonyl)imide are synthesized. Prepared samples show high thermal stability, high ionic conductivity at room temperature and an electrochemical stability window of ~3.51 V vs. Li/Li+. Lithium deposition-striping voltage profiles show the formation of a stable solid electrolyte interface. A Li/GPE/LiFePO4 cell was assembled by low cost thermal lamination technique. This cell can deliver 143 mAh g-1 capacity at room temperature at C/ 20 rate with good discharge efficiency. Use of micro grid mesh type Al current collector in cathode exhibits significant improvement in capacity retention.
Keywords:Lithium metal battery;Polymer electrolyte;Ionic liquid;Voltammetry;Capacity loss
  1. Armand M, Tarascon JM, Nature, 451, 652 (2008)
  2. Bhatt MD, O'Dwyer C, Phys. Chem. Chem. Phys., 17, 4799 (2015)
  3. Osada I, deVries H, Scrosati B, Passerini S, Angew. Chem.-Int. Edit., 55, 500 (2016)
  4. Xue Z, He D, Xie X, J. Mater. Chem. A, 3, 19218 (2015)
  5. Meyer WH, Adv. Mater., 10(6), 439 (1998)
  6. Song JY, Wang YY, Wan CC, J. Power Sources, 77(2), 183 (1999)
  7. Timachova K, Watanabe H, Balsara NP, Macromolecules, 48(21), 7882 (2015)
  8. Osada I, de Vries H, Scrosati B, Passerini S, Angew. Chem.-Int. Edit., 55, 500 (2016)
  9. Mohamed N, Ali SH, Arof A, Indones. J. Phys., 15, 55 (2016)
  10. Zhu YS, Wang XJ, Hou YY, Gao XW, Liu LL, Wu YP, Shimizu M, Electrochim. Acta, 87, 113 (2013)
  11. Croce F, Appetecchi G, Persi L, Scrosati B, Nature, 394, 456 (1998)
  12. Weston J, Steele B, Solid State Ion., 7, 75 (1982)
  13. Das S, Ghosh A, Electrochim. Acta, 171, 59 (2015)
  14. Armand M, Endres F, MacFarlane DR, Ohno H, Scrosati B, Nature Mater., 8, 621 (2009)
  15. Huddleston JG, Willauer HD, Swatloski RP, Visser AE, Rogers RD, Chem. Commun., 1765 (1998).
  16. Seddon KR, J. Chem. Technol. Biotechnol., 68(4), 351 (1997)
  17. Watanabe M, Mizumura T, Solid State Ion., 86, 353 (1996)
  18. Zhang S, Sun N, He X, Lu X, Zhang X, J. Phys. Chem. Ref Data, 35, 1475 (2006)
  19. Zhang D, Haran BS, Durairajan A, White RE, Podrazhansky Y, Popov BN, J. Power Sources, 91(2), 122 (2000)
  20. Arora P, White RE, Doyle M, J. Electrochem. Soc., 145(10), 3647 (1998)
  21. Wen J, Yu Y, Chen C, Mater. Express, 2, 197 (2012)
  22. Han HB, Zhou SS, Zhang DJ, Feng SW, Li LF, Liu K, Feng WF, Nie J, Li H, Huang XJ, Armand M, Zhou ZB, J. Power Sources, 196(7), 3623 (2011)
  23. Sugimoto T, Atsumi Y, Kono M, Kikuta M, Ishiko E, Yamagata M, Ishikawa M, J. Power Sources, 195(18), 6153 (2010)
  24. Shin JH, Henderson WA, Scaccia S, Prosini PP, Passerini S, J. Power Sources, 156(2), 560 (2006)
  25. Balo L, Shalu, Gupta H, Singh VK, Singh RK, Electrochim. Acta, 230, 123 (2017)
  26. Shalu S, Balo L, Gupta H, Singh HK, Singh RK, RSC Adv., 6, 73028 (2016)
  27. Evans J, Vincent CA, Bruce PG, Polymer, 28, 2324 (1987)
  28. Zhang J, Zhao J, Yue L, Wang Q, Chai J, Liu Z, Zhou X, Li H, Guo Y, Cui G, Adv. Eng. Mater., 5 (2015)
  29. Sirisopanaporn C, Fernicola A, Scrosati B, J. Power Sources, 186(2), 490 (2009)
  30. Vallee A, Besner S, Prud'Homme J, Electrochim. Acta, 37, 1579 (1992)
  31. Chaurasia SK, Singh RK, Chandra S, Solid State Ion., 183(1), 32 (2011)
  32. Chaurasia SK, Singh RK, Chandra S, J. Polym. Sci. B: Polym. Phys., 49(4), 291 (2011)
  33. Paillard E, Zhou Q, Henderson WA, Appetecchi GB, Montanino M, Passerini S, J. Electrochem. Soc., 156(11), A891 (2009)
  34. Zhu CB, Cheng H, Yang Y, J. Electrochem. Soc., 155(8), A569 (2008)
  35. Polu AR, Rhee HW, Int. J. Hydrog. Energy, 42(10), 7212 (2017)
  36. Singh B, Sekhon SS, J. Phys. Chem. B, 109(34), 16539 (2005)
  37. Abitelli E, Ferrari S, Quartarone E, Mustarelli P, Magistris A, Fagnoni M, Albini A, Gerbaldi C, Electrochim. Acta, 55(19), 5478 (2010)
  38. Gupta H, Shalu S, Balo L, Singh VK, Chaurasia SK, Singh RK, RSC Adv., 6, 87878 (2016)
  39. Croce F, Settimi L, Scrosati B, Electrochem. Commun., 8, 364 (2006)
  40. Fasciani C, Panero S, Hassoun J, Scrosati B, J. Power Sources, 294, 180 (2015)
  41. Chintapalli M, Timachova K, Olson KR, Mecham SJ, Devaux D, DeSimone JM, Balsara NP, Macromolecules, 49(9), 3508 (2016)
  42. Wang QJ, Song WL, Fan LZ, Shi Q, J. Power Sources, 279, 405 (2015)
  43. Xiang HF, Yin B, Wang H, Lin HW, Ge XW, Xie S, Chen CH, Electrochim. Acta, 55(18), 5204 (2010)
  44. Yang PX, Liu L, Li LB, Hou J, Xu YP, Ren XF, An MZ, Li N, Electrochim. Acta, 115, 454 (2014)
  45. Jin B, Jin EM, Park KH, Gu HB, Electrochem. Commun., 10, 1537 (2008)
  46. Xiong S, Xie K, Blomberg E, Jacobsson P, Matic A, J. Power Sources, 252, 150 (2014)
  47. Shin JH, Henderson WA, Scaccia S, Prosini PP, Passerini S, J. Power Sources, 156(2), 560 (2006)
  48. Li MT, Yang L, Fang SH, Dong SM, Jin YD, Hirano S, Tachibana K, J. Power Sources, 196(15), 6502 (2011)
  49. Ma Y, Li LB, Gao GX, Yang XY, You Y, Electrochim. Acta, 187, 535 (2016)
  50. Ng KS, Moo CS, Chen YP, Hsieh YC, Appl. Energy, 86(9), 1506 (2009)