화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.65, 254-263, September, 2018
DOI10.1016/j.jiec.2018.04.036  Export Citation
A modified heteropoly acid catalyst with cetyltrimethylammonium bromide for methacrolein to methacrylic acid
Yun-Li Cao1, 2, Lei Wang1, Li-Long Zhou1, 3, Bao-Hua Xu1, Yan-Yan Diao1, and Suo-Jiang Zhang1, †
  • 1Beijing Key Laboratory of Ionic Liquids Clean Processes, CAS Key Laboratory of Green Process and Engineering, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, 100190, Beijing, People’s Republic of China
  • 2Pingdingshan University, 467000, Pingdingshan, People’s Republic of China
  • 3University of Chinese Academy of Sciences, 100049, Beijing, People’s Republic of China
E-mail:
A novel type of heteropolyacids, CTAB-CsH3PMo11VO40 (CTA-CsPAV), was developed by a method of emulsion synthesis using cetyltrimethyl ammonium bromide (CTAB) as the structure promoter, which was applied as a catalyst in the oxidation of methacrolein (MAL) to methacrylic acid (MAA) with fixed- bed reactor. The structure and property of CTA-CsPAV were characterized by FT-IR, XRD, nitrogen adsorption-desorption, NH3-TPD, SEM, XPS, and so on. The structure-performance relationship of CTA- CsPAV was systematically studied, wherein the influence of surface area, acidity, redox property of CTA- CsPAV were focused and discussed. Importantly, the long-term performance of CTA-CsPAV was also investigated.
Keywords:Heteropolyacids;Cetyltrimethyl ammonium bromide;Methacrolein;Methacrylic acid
  1. Nagai K, Appl. Catal. A: Gen., 221(1-2), 367 (2001)
  2. Deuber LM, Gaube JW, Martin FG, Hibst H, Stud. Surf. Sci. Catal., 101, 981 (1996)
  3. Zhang H, Yan RY, Yang L, Diao YY, Wang L, Zhang SJ, Ind. Eng. Chem. Res., 52(12), 4484 (2013)
  4. Miura T, Yasukawa T, Hasegawa W, Ninomiya K, Ooyachi H, Imai T, Tatsumi Y, Catal. Commun., 13, 59 (2011)
  5. Stytsenko VD, Lee WH, Lee JW, Kinet. Catal., 42, 212 (2001)
  6. Boehnke H, Gaube J, Petzoldt J, Ind. Eng. Chem. Res., 45(26), 8794 (2006)
  7. Marosi L, Cox G, Tenten A, Hibst H, J. Catal., 194(1), 140 (2000)
  8. Guo X, Huang C, Chen B, J. Korean Chem. Eng., 5, 675 (2008)
  9. Guo X, Huang C, Yingxia Li Y, Korean J. Chem. Eng., 25(4), 697 (2008)
  10. Cao YL, Wang L, Xu BH, Zhang SJ, Chem. Eng. J., 334, 1657 (2018)
  11. Zhou L, Wang L, Cao Y, Diao Y, Yan R, Zhang S, Mol. Catal., 438, 47 (2017)
  12. Marchal-Roch C, Laronze N, Guillou N, Teze A, Herve G, Appl. Catal. A: Gen., 199(1), 33 (2000)
  13. Marchal-Roch C, Laronze N, Guillou N, Teze A, Herve G, Appl. Catal. A: Gen., 203(1), 143 (2000)
  14. Marosi L, Arean CO, J. Catal., 213(2), 235 (2003)
  15. Jing F, Katryniok B, Bordes-Richard E, Paul S, Catal. Today, 203, 32 (2003)
  16. Jing F, Katryniok B, Dumeignil F, Bordes-Richard E, Paul S, J. Catal., 309, 121 (2014)
  17. Jing F, Katryniok B, Bordesrichard E, Dumeignil F, Paul S, Catalysts, 5, 460 (2015)
  18. Sultan M, Paul S, Fournier M, Vanhove D, Appl. Catal. A: Gen., 259(2), 141 (2004)
  19. Cao YL, Wang L, Zhou LL, Zhang GJ, Xu BH, Zhang SJ, Ind. Eng. Chem. Res., 56(3), 653 (2017)
  20. Kanno M, Yasukawa T, Ninomiya W, Ooyachi K, Kamiya Y, J. Catal., 273(1), 1 (2010)
  21. Firouzabadi H, Iranpoor N, Amani K, J. Mol. Catal. A-Chem., 195(1-2), 289 (2003)
  22. Guo ML, Green Chem., 6, 271 (2004)
  23. Liu K, Abass M, Zou Q, Yan X, Green Energ. Environ., 1, 58 (2017)
  24. Shah AT, Mujahid A, Farooq MU, Ahmad W, Li B, Irfan M, Qadir MA, J. Sol-Gel Sci. Technol., 63, 194 (2012)
  25. Masteri-Farahani M, Ghorbani M, Ezabadi A, Farrokhinia N, Ghaemmaghami AS, C.R. Chim., 17, 1136 (2014)
  26. Palermo V, Sathicq GA, Constantieux T, Rodriguez J, Vazquez PG, Romanelli GP, Catal. Lett., 146, 1 (2016)
  27. Cheng M, Shi T, Wang S, Guan H, Fan C, Wang X, Catal. Commun., 12, 148 (2011)
  28. Cheng MX, Shi T, Guan HY, Wang ST, Wang XH, Jiang ZJ, Appl. Catal. B: Environ., 107(1-2), 104 (2011)
  29. Zhang XY, Zhang D, Sun Z, Xue LF, Wang XH, Jiang ZJ, Appl. Catal. B: Environ., 196, 50 (2016)
  30. Sun Z, Wang ST, Wang XH, Jiang ZJ, Fuel, 164, 262 (2016)
  31. Duan X, Sun G, Sun Z, Li J, Wang S, Wang X, Li S, Jiang Z, Catal. Commun., 42, 125 (2013)
  32. Zhao J, Guan H, Shi W, Cheng M, Wang X, Li S, Catal. Commun., 20, 103 (2012)
  33. Han XX, Chen KK, Yan W, Hung CT, Liu LL, Wu PH, Lin KC, Liu SB, Fuel, 165, 115 (2016)
  34. Sun Z, Duan X, Zhao J, Wang X, Jiang Z, Biomass Bioenergy, 76, 31 (2015)
  35. Li H, Zhang P, Zhang L, Zhou T, Hu D, J. Mater. Chem., 19, 4575 (2009)
  36. Lu Y, Sun Z, Huo M, RSC Adv., 5, 30869 (2015)
  37. Zhou LL, Wang L, Zhang SJ, Yan RY, Diao YY, J. Catal., 329, 431 (2015)
  38. Dolbecq A, Dumas E, Mayer CR, Mialane P, Chem. Rev., 110(10), 6009 (2010)
  39. Uchida S, Inumaru K, Misono M, J. Phys. Chem. B, 104(34), 8108 (2000)
  40. Kubies D, Jerome R, Grandjean J, Langmuir, 18(16), 6159 (2002)
  41. Simonutti R, Comotti A, Bracco AS, Sozzani P, Chem. Mater., 13, 771 (2001)
  42. Zhu JX, He HP, Zhu LZ, Wen XY, Deng F, J. Colloid Interface Sci., 286(1), 239 (2005)
  43. Laronze N, Marchal-Roch C, Guillou N, Liu FX, Herve G, J. Catal., 220(1), 172 (2003)
  44. Jing F, Katryniok B, Dumeignil F, Bordesrichard E, Paul S, Catal. Sci. Technol., 4, 2938 (2014)
  45. Kozhevnikov IV, J. Mol. Catal. A-Chem., 262(1-2), 86 (2007)
  46. Bondarenka V, Lith. J. Phys., 47, 59 (2007)
  47. Khattak GD, Mekki A, Wenger LE, J. Non-Cryst. Solids, 355, 2148 (2009)
  48. Ito KIT, Misono M, J. Phys. Chem. B, 101, 9958 (1997)