화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.65, 397-405, September, 2018
DOI10.1016/j.jiec.2018.05.012  Export Citation
Oligomerization of 1-hexene over designed SBA-15 acid catalysts
Mee-Hyun Kwon1, Ho-Jeong Chae1, 2, †, and Min Bum Park3, †
  • 1CO2 Energy Vector Research Group, Carbon Resources Institute, Korea Research Institute of Chemical Technology, Daejeon 34114, South Korea
  • 2KRICT School, University of Science and Technology, Daejeon 34113, South Korea
  • 3Innovation Center for Chemical Engineering, Department of Energy and Chemical Engineering, Incheon National University, Incheon 22012, South Korea
E-mail:,
SBA-15 acid catalysts were prepared using two different post-synthesis methods, alumination followed by ion-exchange (H-Al/SBA-15) and styrene polymerization followed by sulfonation (H-SP/SBA-15). For the H-Al/SBA-15, 1-hexene conversion and C10+ selectivity tended to increase with increasing pore size, although there were no significant differences higher than 7 nm. For the H-SP/SBA-15, the conversion and C10+ selectivity increased with increasing amounts of polymers but there was also an optimum range (20.25 wt.%). The overall results demonstrate that controlling the acid properties of the mesoporous SBA-15 is much more critical to 1-hexene oligomerization than improving diffusion limitation by modifying textural properties.
Keywords:Acid site;1-Hexene;Oligomerization;SBA-15;Textural property
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