화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.35, No.9, 1836-1843, September, 2018
DOI10.1007/s11814-018-0094-9  Export Citation
Preparation and characterization of hydrophilic polydopamine-coated Fe3O4/oxide graphene imprinted nanocomposites for removal of bisphenol A in waters
Suyu Ren, Jing Tao1, Ying Cui, Jinsuo Gao, Xiaona Li, and Feng Tan†
  • Key Laboratory of Industrial Ecology and Environmental Engineering (MOE), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, China
  • 1Department of Chemistry & Life Science, Anshan Normal College, Anshan 114005, China
E-mail:
Bisphenol A (BPA), a known endocrine disruptor, is of global concern because it poses serious threats to the ecological environment and human health. In this work, hydrophilic polydopamine-coated Fe3O4/oxide graphene (IPDA@MGO) magnetic imprinted nanocomposites were prepared by the self-polymerization of dopamine on the surface of Fe3O4/GO in Tris-HCl buffer using BPA as a template for selective adsorption of BPA in water. IPDA@MGO showed specific recognition toward BPA with a high imprinting factor of 3.2 compared with nonimprinted polymer. The capacity of IPDA@MGO toward BPA was 41.2mg/g and the adsorption reached equilibrium within 30 min. The adsorption agreed well with the Freundlich and pseudo-second order kinetic models. The good adsorption performance was attributed to the abundant binding sites and good dispersibility of IPDA@MGO nanocomposites derived from its excellent hydrophilicity. The nanocomposites could be removed rapidly by an external magnet and regenerated for repeated adsorption of BPA in water. The proposed method has potential applications for efficient removal of BPA in environmental waters.
Keywords:Adsorption;Bisphenol A;Molecular Imprinting;Nanocomposites;Polydopamine
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