Corrosion inhibition properties of a green hybrid pigment based on Pr-Urtica Dioica plant extract

M. Motamedi; B. Ramezanzadeh; M. Mahdavian

Journal of Industrial and Engineering Chemistry, Vol.66, 116-125, October, 2018

DOI10.1016/j.jiec.2018.05.021 Export Citation

Corrosion inhibition properties of a green hybrid pigment based on Pr-Urtica Dioica plant extract

M. Motamedi, B. Ramezanzadeh^†, and M. Mahdavian^†

Surface Coating and Corrosion Department, Institute for Color Science and Technology, P.O. Box 16765-654, Tehran, Iran

E-mail:,

The main aim of this research is studying the corrosion inhibition properties of the combination of praseodymium nitrate (PrN) and Urtica Dioica (UrDi) on mild steel in sodium chloride solution. Fourier transform infrared (FT-IR), ultraviolet-visible (UV-Vis), thermogravimetric analysis/differential ther- mogravimetry (TGA/DTG) and X-ray photoelectron spectroscopy (XPS) results confirmed complex formation between Pr cations and UrDi (Pr-UrDi). Electrochemical results revealed that the Pr-UrDi hybrid complex had significant influence on the mild steel corrosion protection (by inhibition efficiency of ca. 94%) in NaCl solution.

Keywords:Hybrid green inhibitor;Praseodymium nitrate;Urtica Dioica;EIS;XPS

[References]

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Deflorian F, Rossi S, Fedrizzi L, Bonora PL, Prog. Org. Coat., 52, 271 (2005)
Verma C, Ebenso EE, Bahadur I, Obot IB, Quraishi MA, J. Mol. Liq., 212, 209 (2015)
Ismail A, ARPN J. Eng. Appl. Sci., 11, 8710 (2016)
Zaabar A, Aitout R, Makhloufi L, Pigm. Resin Technol.., 43, 127 (2014)
Salehi E, Naderi R, Ramezanzadeh B, Appl. Surf. Sci., 396, 1499 (2017)
Nasibi M, Mohammady M, Ghasemic E, Ashrafid A, Zaareie D, Rashed G, J. Adhes. Sci. Technol., 27, 1873 (2013)
Leidheiser H, Corrosion, 39, 189 (1983)
Sharma SK (Ed.), Green Corrosion Chemistry and Engineering: Opportunities and Challenges, Wiley VCH. Pub., Weinheim, Germany, 2011.
Askari F, Ghasemi E, Ramezanzadeh B, Mahdavian M, Dyes Pigment., 109, 189 (2014)
Bastos AC, Ferreira MG, Simoes AM, Corrosion Sci., 48, 1500 (2006)
Mahdavian M, Naderi R, Corrosion Sci., 53, 1194 (2011)
Alibakhshi E, Ghasemi E, Mahdavian M, Corrosion Sci., 77, 222 (2013)
Lata S, Chaudhary RS, Indian J. Chem. Technol., 15(4), 364 (2008)
Ramezanzadeh B, Ghasemi E, Askari F, Mahdavian M, Dyes Pigment., 122, 331 (2015)
Blustein G, Amo BD, Romagnoli R, Pigm. Resin Technol., 29, 100 (2000)
Turra C, Int. J. Environ. Health Res., 28, 23 (2018)
Kendig MW, Buchheit RG, Corrosion, 59, 379 (2003)
TaekRim K, HoKoo K, SunPark J, Saf. Health Work, 4, 12 (2013)
Tkacz J, Minda J, Fintova S, Wasserbauer J, Materials, 9, 925 (2016)
Motamedi M, Attar MM, Rostami M, Prog. Org. Coat., 102, 178 (2017)
Ramezanzadeh B, Ghasemi E, Mandavian M, Changizi E, Moghadam MHM, Chem. Eng. J., 281, 869 (2015)
Mermoux M, Chabre Y, Rousseau A, Carbon, 29, 469 (1991)
Pacheco AFC, Cuaspud JAG, Lopez EV, J. Phys.: Conf. Ser., 687, 012046 (2016)
Vanhoyland G, Pagnaer J, D’Haen J, Mullens S, Mullens J, J. Solid State Chem., 178, 166 (2005)
Pinheiro F, de Souza FM, Martins TS, Fantini MCA, Isolani PC, J. Therm. Anal. Calorim., 99, 385 (2010)
Trivedi MK, Tallapragada RM, Branton A, Trivedi D, Nayak G, Latiyal O, Jana S, Int. J. Mater. Sci. Appl., 4, 390 (2015)
Abdullah WRW, Zakaria A, Ghazali MSM, Int. J. Mol. Sci., 13(4), 5278 (2012)
Quievryn C, Bernard S, Miele P, Nanomater. Nanotechnol., 4, 1 (2014)
Zinatloo-Ajabshir S, Salavati-Niasari M, Ceram. Int., A41, 567 (2015)
Popa M, Kakihana M, Solid State Ion., 141-142, 265 (2001)
Abboud Y, Abourriche A, Ainane T, Charrouf M, Bennamara A, Tanane O, Hammouti B, Chem. Eng. Commun., 196(7), 788 (2009)
Jalili M, Rostami M, Ramezanzadeh B, Appl. Surf. Sci., 37, 95 (2015)
Phytochemicals and Constituents of Nettle, Urtica dioica L., Urticae radix. www.mdidea.com, 2015.
Brebu M, Vasile C, Thermal Degradation of Lignin: A Review, Petru Pani Institute of Macromolecular Chemistry, 41A, Romania, 2009.
Chen CM, Huang JQ, Zhang Q, Gong WZ, Yang QH, Wang MZ, Yang YG, Carbon, 50, 659 (2012)
Lopez GP, Castner DG, Ratner BD, Surf. Interface Anal., 17, 267 (1991)
Yan L, Yu R, Liu G, Xing X, Scr. Mater., 58, 707 (2008)
Nilsson JO, Tornkvist C, Liedberg B, Appl. Surf. Sci., 37, 306 (1989)
Hassan MS, Akhtar MS, Shim KB, Yang OB, Nanoscale Res. Lett., 5, 735 (2010)
Wagner CD, Riggs WH, Davis LE, Moulder JF, Muilinberg GE, Handbook of X-ray Photoelectron Spectroscopy, Perkin.Elmer Corporation, Minnesota, 1973.
Crist BV, Handbooks of Monochromatic XPS Spectra: The Elements and Native Oxides, XPS, International, Inc., California, USA, 1999.
Yu B, Wang X, Qian X, Xing W, Yang H, Ma L, Lin Y, Jiang S, Song L, Hu Y, Lo S, RSC Adv., 4, 31782 (2014)
Drewniak S, Muzyka R, Stolarczyk A, Pustelny T, Kotyczka-Moranska M, Setkiewicz M, Sensors, 16(1), E103 (2016)
Sherif EM, Int. J. Electrochem. Sci., 6, 3077 (2011)
Amin MA, El-Rehim SSA, El-Sherbini EEF, Bayoumi RS, Electrochim. Acta, 52(11), 3588 (2007)
Ramezanzadeh B, Vakili H, Amini R, J. Ind. Eng. Chem., 30, 225 (2015)
Mahdavian M, Tehrani-Bagha AR, Holmberg K, J. Surfactants Deterg., 14, 605 (2011)
Nasibi M, Mohammady M, Ghasemic E, Ashrafid A, Zaareie D, Rashed G, J. Adhes. Sci. Technol., 27, 1873 (2013)
Macdonald JR, Impedance Spectroscopy, John Wiley & Sons, Inc., New York, 1987.
Motamedi M, Attar MM, RSC Adv., 6, 44732 (2016)
Rosalbino F, Scavino G, Mortarino G, Angelini E, Lunazzi G, J. Solid State Electrochem., 15, 703 (2011)
Popova A, Sokolova E, Raicheva S, Christov M, Corrosion Sci., 45, 33 (2003)
Motamedi M, Tehrani-Bagha AR, Mahdavian M, Prog. Org. Coat., 77, 712 (2014)
Motamedi M, Tehrani-Bagha AR, Mahdavian M, Corrosion Sci., 70, 46 (2013)
Hirschorn B, Orazem ME, Tribollet B, Vivier V, Frateur I, Musiani M, Electrochim. Acta, 55(21), 6218 (2010)
Motamedi M, Tehrani-Bagha AR, Mandavian M, Electrochim. Acta, 58, 488 (2011)
Alibakhshi E, Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B, Mahdavian M, Motamedi M, J. Mol. Liq., 255, 185 (2018)
Markhali BP, Naderi R, Mahdavian M, Sayebani M, Arman SY, Corrosion Sci., 75, 269 (2013)
McCafferty E, Introduction to Corrosion Science, 1st ed., Springer Science Pub., 2010.

[Referenced By]

[1] Bardel E, Corrosion and Protection, Springer-Verlag Pub., London, 2004.

[2] Deflorian F, Rossi S, Fedrizzi L, Bonora PL, Prog. Org. Coat., 52, 271 (2005)

[3] Verma C, Ebenso EE, Bahadur I, Obot IB, Quraishi MA, J. Mol. Liq., 212, 209 (2015)

[4] Ismail A, ARPN J. Eng. Appl. Sci., 11, 8710 (2016)

[5] Zaabar A, Aitout R, Makhloufi L, Pigm. Resin Technol.., 43, 127 (2014)

[6] Salehi E, Naderi R, Ramezanzadeh B, Appl. Surf. Sci., 396, 1499 (2017)

[7] Nasibi M, Mohammady M, Ghasemic E, Ashrafid A, Zaareie D, Rashed G, J. Adhes. Sci. Technol., 27, 1873 (2013)

[8] Leidheiser H, Corrosion, 39, 189 (1983)

[9] Sharma SK (Ed.), Green Corrosion Chemistry and Engineering: Opportunities and Challenges, Wiley VCH. Pub., Weinheim, Germany, 2011.

[10] Askari F, Ghasemi E, Ramezanzadeh B, Mahdavian M, Dyes Pigment., 109, 189 (2014)

[11] Bastos AC, Ferreira MG, Simoes AM, Corrosion Sci., 48, 1500 (2006)

[12] Mahdavian M, Naderi R, Corrosion Sci., 53, 1194 (2011)

[13] Alibakhshi E, Ghasemi E, Mahdavian M, Corrosion Sci., 77, 222 (2013)

[14] Lata S, Chaudhary RS, Indian J. Chem. Technol., 15(4), 364 (2008)

[15] Ramezanzadeh B, Ghasemi E, Askari F, Mahdavian M, Dyes Pigment., 122, 331 (2015)

[16] Blustein G, Amo BD, Romagnoli R, Pigm. Resin Technol., 29, 100 (2000)

[17] Turra C, Int. J. Environ. Health Res., 28, 23 (2018)

[18] Kendig MW, Buchheit RG, Corrosion, 59, 379 (2003)

[19] TaekRim K, HoKoo K, SunPark J, Saf. Health Work, 4, 12 (2013)

[20] Tkacz J, Minda J, Fintova S, Wasserbauer J, Materials, 9, 925 (2016)

[21] Motamedi M, Attar MM, Rostami M, Prog. Org. Coat., 102, 178 (2017)

[22] Ramezanzadeh B, Ghasemi E, Mandavian M, Changizi E, Moghadam MHM, Chem. Eng. J., 281, 869 (2015)

[23] Mermoux M, Chabre Y, Rousseau A, Carbon, 29, 469 (1991)

[24] Pacheco AFC, Cuaspud JAG, Lopez EV, J. Phys.: Conf. Ser., 687, 012046 (2016)

[25] Vanhoyland G, Pagnaer J, D’Haen J, Mullens S, Mullens J, J. Solid State Chem., 178, 166 (2005)

[26] Pinheiro F, de Souza FM, Martins TS, Fantini MCA, Isolani PC, J. Therm. Anal. Calorim., 99, 385 (2010)

[27] Trivedi MK, Tallapragada RM, Branton A, Trivedi D, Nayak G, Latiyal O, Jana S, Int. J. Mater. Sci. Appl., 4, 390 (2015)

[28] Abdullah WRW, Zakaria A, Ghazali MSM, Int. J. Mol. Sci., 13(4), 5278 (2012)

[29] Quievryn C, Bernard S, Miele P, Nanomater. Nanotechnol., 4, 1 (2014)

[30] Zinatloo-Ajabshir S, Salavati-Niasari M, Ceram. Int., A41, 567 (2015)

[31] Popa M, Kakihana M, Solid State Ion., 141-142, 265 (2001)

[32] Abboud Y, Abourriche A, Ainane T, Charrouf M, Bennamara A, Tanane O, Hammouti B, Chem. Eng. Commun., 196(7), 788 (2009)

[33] Jalili M, Rostami M, Ramezanzadeh B, Appl. Surf. Sci., 37, 95 (2015)

[34] Phytochemicals and Constituents of Nettle, Urtica dioica L., Urticae radix. www.mdidea.com, 2015.

[35] Brebu M, Vasile C, Thermal Degradation of Lignin: A Review, Petru Pani Institute of Macromolecular Chemistry, 41A, Romania, 2009.

[36] Chen CM, Huang JQ, Zhang Q, Gong WZ, Yang QH, Wang MZ, Yang YG, Carbon, 50, 659 (2012)

[37] Lopez GP, Castner DG, Ratner BD, Surf. Interface Anal., 17, 267 (1991)

[38] Yan L, Yu R, Liu G, Xing X, Scr. Mater., 58, 707 (2008)

[39] Nilsson JO, Tornkvist C, Liedberg B, Appl. Surf. Sci., 37, 306 (1989)

[40] Hassan MS, Akhtar MS, Shim KB, Yang OB, Nanoscale Res. Lett., 5, 735 (2010)

[41] Wagner CD, Riggs WH, Davis LE, Moulder JF, Muilinberg GE, Handbook of X-ray Photoelectron Spectroscopy, Perkin.Elmer Corporation, Minnesota, 1973.

[42] Crist BV, Handbooks of Monochromatic XPS Spectra: The Elements and Native Oxides, XPS, International, Inc., California, USA, 1999.

[43] Yu B, Wang X, Qian X, Xing W, Yang H, Ma L, Lin Y, Jiang S, Song L, Hu Y, Lo S, RSC Adv., 4, 31782 (2014)

[44] Drewniak S, Muzyka R, Stolarczyk A, Pustelny T, Kotyczka-Moranska M, Setkiewicz M, Sensors, 16(1), E103 (2016)

[45] Sherif EM, Int. J. Electrochem. Sci., 6, 3077 (2011)

[46] Amin MA, El-Rehim SSA, El-Sherbini EEF, Bayoumi RS, Electrochim. Acta, 52(11), 3588 (2007)

[47] Ramezanzadeh B, Vakili H, Amini R, J. Ind. Eng. Chem., 30, 225 (2015)

[48] Mahdavian M, Tehrani-Bagha AR, Holmberg K, J. Surfactants Deterg., 14, 605 (2011)

[49] Nasibi M, Mohammady M, Ghasemic E, Ashrafid A, Zaareie D, Rashed G, J. Adhes. Sci. Technol., 27, 1873 (2013)

[50] Macdonald JR, Impedance Spectroscopy, John Wiley & Sons, Inc., New York, 1987.

[51] Motamedi M, Attar MM, RSC Adv., 6, 44732 (2016)

[52] Rosalbino F, Scavino G, Mortarino G, Angelini E, Lunazzi G, J. Solid State Electrochem., 15, 703 (2011)

[53] Popova A, Sokolova E, Raicheva S, Christov M, Corrosion Sci., 45, 33 (2003)

[54] Motamedi M, Tehrani-Bagha AR, Mahdavian M, Prog. Org. Coat., 77, 712 (2014)

[55] Motamedi M, Tehrani-Bagha AR, Mahdavian M, Corrosion Sci., 70, 46 (2013)

[56] Hirschorn B, Orazem ME, Tribollet B, Vivier V, Frateur I, Musiani M, Electrochim. Acta, 55(21), 6218 (2010)

[57] Motamedi M, Tehrani-Bagha AR, Mandavian M, Electrochim. Acta, 58, 488 (2011)

[58] Alibakhshi E, Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B, Mahdavian M, Motamedi M, J. Mol. Liq., 255, 185 (2018)

[59] Markhali BP, Naderi R, Mahdavian M, Sayebani M, Arman SY, Corrosion Sci., 75, 269 (2013)

[60] McCafferty E, Introduction to Corrosion Science, 1st ed., Springer Science Pub., 2010.