화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.66, 158-167, October, 2018
DOI10.1016/j.jiec.2018.05.025  Export Citation
Effects of SBA-15 physicochemical properties on performance of Pd/SBA-15 catalysts in 2-ethyl-anthraquinone hydrogenation
Enxian Yuan1, 2, Chan Wu1, Guozhu Liu1, 3, Guozhu Li1, 3, and Li Wang1, 3, †
  • 1Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
  • 2School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, China
  • 3Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China
E-mail:
A series of SBA-15 mesoporous silicas with pore sizes ranging between 7 and 26 nm were synthesized and modified by incorporating Al or Mg and functionalization with n-dodecyltrimethoxysilane. Pd/SBA-15 catalysts were prepared and the effects of the pore structure, Al/Mg modifiers and Pd particles distribution on 2-ethyl-anthraquinone hydrogenation have been studied. The catalytic performance improves with enlarging SBA-15 pore size and reaches a plateau at 22.3 nm. The incorporation of Mg into SBA-15 increases the catalytic performance of catalysts. But, the incorporation of Al brings about opposite results. The functionalization of SBA-15 with n-dodecyltrimethoxysilane further enhances the catalytic performance.
Keywords:Catalytic hydrogenation;SBA-15 support;2-Ethyl-anthraquinone;Pore structure;Modification
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