화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.66, 333-342, October, 2018
DOI10.1016/j.jiec.2018.05.048  Export Citation
Plate column adsorption of Pb(II) from industrial wastewater on sponge-type composite adsorbent: Optimization and application
Nana Wang1, 2, Xingjian Xu3, Li Yang3, Lizhu Yuan3, Tangfu Xiao2, Haiyan Li3, and Hongwen Yu3, †
  • 1Key Laboratory of Wetland Ecology and Environment, Northeast Institute of Geography and Agroecology, Chinese Academy of Sciences, Changchun 130102, China
  • 2Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, School of Environmental Science and Engineering, Guangzhou University, Guangzhou 510006, China
  • 3Key Laboratory of Wetland Ecology and Environment, Northeast Institute of Geography and Agroecology, Chinese Academy of Sciences, Changchun 130102, China, Korea
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A sponge-type composite adsorbent xanthate-modified chitosan @ titanate nanotubes (XCTS@TNTs) was prepared via a simple and low-cost procedure, and its adsorption capacity was evaluated in batch and continuous plate column systems. The three-dimensional network macroporous structure made it easy to separate from the solution and suitable for the column-based treatment. The excellent adsorption capacity of Pb(II) was as high as 342.47 mg/g and could be obtained in wide ranges of pH and temperature. Interestingly, XCTS@TNTs exhibited outstanding selectivity for Pb(II) rather than other divalent heavy metal ions. Adsorption mechanism was elucidated by the FTIR and XPS analyses. The column adsorption results indicated that the treatment effect was proportional to bed height and inversely to flow rate and influent concentration. XCTS@TNTs was remarkably effective in the removal of Pb(II) from actual industrial effluents to meet the discharge requirements and contributed to the recovery of Pb(II). The treatment volumes of simulated actual battery wastewater and smelting effluent by 2.40 g XCTS@TNTs were as high as 6360 and 49584 mL for Pb(II) with the concentration of 30.55 and 4.49 mg/L, respectively. This work developed a highly practical process for removing heavy metal ions from practical wastewaters.
Keywords:Heavy metal removal;Industrial wastewater;Plate column;Chitosan sponge;Titanate nanotubes
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