Journal of Polymer Science Part B: Polymer Physics, Vol.34, No.6, 1127-1131, 1996
Monte-Carlo Study of Polyelectrolyte Gels
The discontinuous transition between dense and dilute phases in polyelectrolyte gels is observed in Bond-Fluctuation Method Monte Carlo simulations of gels. The transition is driven by the competition between local attractive interactions of a poor-quality solvent and global repulsive interactions from counter-ion pressure. A procedure is introduced that prevents local attractive interactions from destroying ergodicity. Under good solvent conditions, lengths and volumes of gels are found to follow self-avoiding random walk scaling.
Keywords:DYNAMIC PROPERTIES;POLYMER MELTS