Effects of HLB value on oil-in-water emulsions: Droplet size, rheological behavior, zeta-potential, and creaming index

In Kwon Hong; Su In Kim; Seung Bum Lee

Journal of Industrial and Engineering Chemistry, Vol.67, 123-131, November, 2018

DOI10.1016/j.jiec.2018.06.022 Export Citation

Effects of HLB value on oil-in-water emulsions: Droplet size, rheological behavior, zeta-potential, and creaming index

In Kwon Hong , Su In Kim, and Seung Bum Lee^†

Department of Chemical Engineering, Dankook University, Yongin 16890, Republic of Korea

E-mail:

Using mixed nonionic surfactants Span/Tween, we investigated the effects of HLB value on the O/W emulsion stability and rheological behaviors. In this study, MS-01 (Span 60 & Tween 60) and MS-02 (Span 80 & Tween 80) was used as mixed nonionic surfactants. We considered required HLB value 10.85 and selected corresponding HLB value range 8-13. The droplet size distributions, droplet morphology, rheological properties, zeta-potential and creaming index of the emulsion samples were obtained to understand the mechanism and interaction of droplets in O/W emulsion. The results indicated that optimal HLB number for O/W emulsions was 10.8 and 10.7, while using MS-01 surfactant and MS-02 surfactant respectively. MS-01 (HLB = 10.8) sample and MS-02 (HLB = 10.7) sample showed smallest droplet size and highest zeta-potential value. Rheological properties are measured to understand rheological behaviors of emulsion samples. All emulsion samples showed no phase separation until 30 days storage time at 25 °C.

Keywords:HLB value;Emulsifying stability;Rheological behavior;SPAN-TWEEN surfactants

[References]

Zhang Z, Wang X, Yu J, Chen S, Ge H, Jiang L, LWT Food Sci. Technol., 78, 241 (2017)
Teo A, Lee SJ, Goh KKT, Wolber FM, Food Chem., 221, 1269 (2017)
Hebishy E, Buffa M, Juan B, Blasco-Moreno A, Trujillo AJ, LWT Food Sci. Technol., 76, 57 (2017)
Powell KC, Chauhan A, Colloids Surf. A: Physicochem. Eng. Asp., 504, 458 (2016)
Pal R, J. Colloid Interface Sci., 356(1), 118 (2011)
Ampatzidis CD, Varka EMA, Karapantsios TD, Colloids Surf. A: Physicochem. Eng. Asp., 460, 176 (2014)
Hong IK, Kim SI, Park BR, Choi J, Lee SB, Appl. Chem. Eng., 27(5), 527 (2016)
Baruah A, Shekhawat DS, Pathak AK, Ojha K, J. Pet. Sci. Eng., 146, 340 (2016)
Koneva AS, Safonova EA, Kondrakhina PS, Vovk MA, Lezov AA, Colloids Surf. A: Physicochem. Eng. Asp., 518, 273 (2017)
Griffin WC, J. Soc. Cosmet. Chem., 5, 249 (1954)
Yeon JY, Shin BR, Kim TG, Seo JM, Lee CH, Lee SG, Pyo HB, J. Soc. Cosmet. Sci. Korea, 40(3), 227 (2014)
Housaindokht MR, Pour AN, Solid State Sci., 14, 622 (2012)
Jin X, Streett DA, Dunlap CA, Lyn ME, Biol. Control, 46, 226 (2008)
Orafidiya LO, Oladimeji FA, Int. J. Pharm., 237, 241 (2002)
Schmidts T, Dobler D, Guldan AC, Paulus N, Runkel F, Colloids Surf. A: Physicochem. Eng. Asp., 372, 48 (2010)
Mukherjee M, Mahapatra A, J. Photochem. Photobiol. A-Chem., 294, 1 (2014)
Junyaprasert VB, Singhsa P, Suksiriworapong J, Chantasart D, Int. J. Pharm., 423, 303 (2012)
Ariyaprakai S, Limpachoti T, Pradipasena P, Food Hydrocolloids, 30, 358 (2013)
Nesterenko A, Drelich A, Lu H, Clausse D, Pezron I, Colloids Surf. A: Physicochem. Eng. Asp., 457, 49 (2014)
Royer M, Nollet M, Catte M, Collinet M, Pierlot C, Colloids Surf. A: Physicochem. Eng. Asp., 536, 165 (2018)
Zadymova NM, Skvortsova ZN, Traskine VY, Kulikov-Kostyushko FA, Kulichikhin VG, Malkin AY, J. Pet. Sci. Eng., 149, 522 (2017)
Castel V, Rubiolo AC, Carrara CR, Food Hydrocolloids, 63, 170 (2017)
Plasencia J, pettersen B, Nydal OJ, J. Pet. Sci. Eng., 101, 35 (2013)
Pajouhandeh A, Kavousi A, Schaffie M, Ranjbar M, Colloids Surf. A: Physicochem. Eng. Asp., 520, 597 (2017)
Kim HS, Mason TG, Adv. Colloid Interface Sci., 247, 397 (2017)
Tripathi S, Bhattacharya A, Singh R, Tabor RF, Chem. Eng. Sci., 174, 290 (2017)
Roldan-Cruz C, Vernon-Carter EJ, Alvarez-Ramirez J, Colloids Surf. A: Physicochem. Eng. Asp., 511, 145 (2016)
Wu Z, Wu J, Zhang R, Yuan S, Lu Q, Yu Y, Carbohydr. Polym., 181, 56 (2018)
Zhu XF, Zheng J, Liu F, Qiu CY, Lin WF, Tang CH, Food Hydrocolloids, 74, 37 (2018)
Zhao JY, Dong FJ, Li YY, Kong BH, Liu Q, Process Biochem., 50(10), 1607 (2015)
Shi XY, Gao H, Lazouskaya VI, Kang Q, Jin Y, Wang LP, Comput. Math. Appl., 59, 2290 (2010)
Khan MA, Lee ES, Park SK, Appl. Chem. Eng., 12, 141 (2008)
Koroleva M, Tokarev A, Yurtov E, Colloids Surf. A: Physicochem. Eng. Asp., 481, 237 (2015)

[Related Articles]

[1] Zhang Z, Wang X, Yu J, Chen S, Ge H, Jiang L, LWT Food Sci. Technol., 78, 241 (2017)

[2] Teo A, Lee SJ, Goh KKT, Wolber FM, Food Chem., 221, 1269 (2017)

[3] Hebishy E, Buffa M, Juan B, Blasco-Moreno A, Trujillo AJ, LWT Food Sci. Technol., 76, 57 (2017)

[4] Powell KC, Chauhan A, Colloids Surf. A: Physicochem. Eng. Asp., 504, 458 (2016)

[5] Pal R, J. Colloid Interface Sci., 356(1), 118 (2011)

[6] Ampatzidis CD, Varka EMA, Karapantsios TD, Colloids Surf. A: Physicochem. Eng. Asp., 460, 176 (2014)

[7] Hong IK, Kim SI, Park BR, Choi J, Lee SB, Appl. Chem. Eng., 27(5), 527 (2016)

[8] Baruah A, Shekhawat DS, Pathak AK, Ojha K, J. Pet. Sci. Eng., 146, 340 (2016)

[9] Koneva AS, Safonova EA, Kondrakhina PS, Vovk MA, Lezov AA, Colloids Surf. A: Physicochem. Eng. Asp., 518, 273 (2017)

[10] Griffin WC, J. Soc. Cosmet. Chem., 5, 249 (1954)

[11] Yeon JY, Shin BR, Kim TG, Seo JM, Lee CH, Lee SG, Pyo HB, J. Soc. Cosmet. Sci. Korea, 40(3), 227 (2014)

[12] Housaindokht MR, Pour AN, Solid State Sci., 14, 622 (2012)

[13] Jin X, Streett DA, Dunlap CA, Lyn ME, Biol. Control, 46, 226 (2008)

[14] Orafidiya LO, Oladimeji FA, Int. J. Pharm., 237, 241 (2002)

[15] Schmidts T, Dobler D, Guldan AC, Paulus N, Runkel F, Colloids Surf. A: Physicochem. Eng. Asp., 372, 48 (2010)

[16] Mukherjee M, Mahapatra A, J. Photochem. Photobiol. A-Chem., 294, 1 (2014)

[17] Junyaprasert VB, Singhsa P, Suksiriworapong J, Chantasart D, Int. J. Pharm., 423, 303 (2012)

[18] Ariyaprakai S, Limpachoti T, Pradipasena P, Food Hydrocolloids, 30, 358 (2013)

[19] Nesterenko A, Drelich A, Lu H, Clausse D, Pezron I, Colloids Surf. A: Physicochem. Eng. Asp., 457, 49 (2014)

[20] Royer M, Nollet M, Catte M, Collinet M, Pierlot C, Colloids Surf. A: Physicochem. Eng. Asp., 536, 165 (2018)

[21] Zadymova NM, Skvortsova ZN, Traskine VY, Kulikov-Kostyushko FA, Kulichikhin VG, Malkin AY, J. Pet. Sci. Eng., 149, 522 (2017)

[22] Castel V, Rubiolo AC, Carrara CR, Food Hydrocolloids, 63, 170 (2017)

[23] Plasencia J, pettersen B, Nydal OJ, J. Pet. Sci. Eng., 101, 35 (2013)

[24] Pajouhandeh A, Kavousi A, Schaffie M, Ranjbar M, Colloids Surf. A: Physicochem. Eng. Asp., 520, 597 (2017)

[25] Kim HS, Mason TG, Adv. Colloid Interface Sci., 247, 397 (2017)

[26] Tripathi S, Bhattacharya A, Singh R, Tabor RF, Chem. Eng. Sci., 174, 290 (2017)

[27] Roldan-Cruz C, Vernon-Carter EJ, Alvarez-Ramirez J, Colloids Surf. A: Physicochem. Eng. Asp., 511, 145 (2016)

[28] Wu Z, Wu J, Zhang R, Yuan S, Lu Q, Yu Y, Carbohydr. Polym., 181, 56 (2018)

[29] Zhu XF, Zheng J, Liu F, Qiu CY, Lin WF, Tang CH, Food Hydrocolloids, 74, 37 (2018)

[30] Zhao JY, Dong FJ, Li YY, Kong BH, Liu Q, Process Biochem., 50(10), 1607 (2015)

[31] Shi XY, Gao H, Lazouskaya VI, Kang Q, Jin Y, Wang LP, Comput. Math. Appl., 59, 2290 (2010)

[32] Khan MA, Lee ES, Park SK, Appl. Chem. Eng., 12, 141 (2008)

[33] Koroleva M, Tokarev A, Yurtov E, Colloids Surf. A: Physicochem. Eng. Asp., 481, 237 (2015)