화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.67, 380-387, November, 2018
DOI10.1016/j.jiec.2018.07.012  Export Citation
Polyamidoxime functionalized with phosphate groups by plasma technique for effective U(VI) adsorption
Dadong Shao1, 2, Xiaolin Wang1, †, Xuemei Ren2, †, Sheng Hu1, Jun Wen1, Zhaoyi Tan1, Jie Xiong1, Abdullah M. Asiri3, and Hadi M. Marwani3
  • 1Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900, PR China
  • 2Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, PR China
  • 3Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia
E-mail:,
Finding poly(amidoxime) (PAO) based adsorbent with better performance in U(VI) extraction from seawater is a hot research topic. By employing plasma treatment, the bi-functionalized adsorbents containing amidoxime and phosphate (labelled as PO4/PAO) were successfully synthesized. The obtained PO4/PAO was characterized and applied for the potential extraction of U(VI) from aqueous solution. The results show that PO4 enhanced the hydrophilicity of PAO. PO4/PAO possesses good selective sorption ability for U(VI) and excellent reusability. The findings is helpful to understand optimizing performance of PAO based adsorbents for uranium extraction from seawater.
Keywords:Poly(amidoxime);Phosphate;Uranium extraction;Plasma treatment
  1. OECD/IAEA,, Uranium 2011: Resources, Production and Demand, OECD Publishing, 2012.
  2. Gunathilake C, Gorka J, Dai S, Jaroniec M, J. Mater. Chem. A, 3, 11650 (2015)
  3. Chatterjee S, Bryantsev VS, Brown S, Johnson JC, Grant CD, Mayes RT, Hay BP, Dai S, Saito T, Ind. Eng. Chem. Res., 55(15), 4161 (2016)
  4. Leggett CJ, Endrizzi F, Rao LF, Ind. Eng. Chem. Res., 55(15), 4257 (2016)
  5. Yue YF, Zhang CX, Tang Q, Mayes RT, Liao WP, Liao C, Tsouris C, Stankovich JJ, Chen JH, Hensley DK, Abney CW, Jiang DE, Brown S, Dai S, Ind. Eng. Chem. Res., 55(15), 4125 (2016)
  6. Kim J, Tsouris C, Oyola Y, Janke CJ, Mayes RT, Dai S, Gill G, Kuo LJ, Wood J, Choe KY, Schneider E, Lindner H, Ind. Eng. Chem. Res., 53, 60763 (2014)
  7. Xing Z, Hu J, Wang M, Zhang W, Li S, Gao Q, Wu G, Sci. China Chem., 56, 1504 (2013)
  8. Vukovic S, Watson LA, Kang SO, Custelcean R, Hay BP, Inorg. Chem., 51(6), 3855 (2012)
  9. Xie S, Liu X, Zhang B, Ma H, Ling C, Yu M, Lia L, Li J, J. Mater. Chem. A, 3, 2552 (2015)
  10. Abney CW, Das S, Mayes RT, Kuo LJ, Wood J, Gill G, Piechowicz M, Lin Z, Lin W, Dai S, Phys. Chem. Chem. Phys., 18, 23462 (2016)
  11. Kelley SP, Barber PS, Mullins PHK, Rogers RD, Chem. Commun., 50, 12504 (2014)
  12. Wei Y, Qian J, Huang L, Hua D, RSC Adv., 5, 64286 (2015)
  13. Kim J, Oyola Y, Tsouris C, Hexel CR, Mayes RT, Janke CJ, Dai S, Ind. Eng. Chem. Res., 52(27), 9433 (2013)
  14. Das S, Pandey AK, Vasudevan T, Athawale AA, Manchanda VK, Ind. Eng. Chem. Res., 48(14), 6789 (2009)
  15. Vasudevan T, Pandey AK, Das S, Pujari PK, J. Chem. Eng., 236, 9 (2014)
  16. Xiong J, Hu S, Liu Y, Yu J, Yu H, Xie L, Wen J, Wang X, ACS Sustain. Chem. Eng., 5, 1924 (2017)
  17. Budnyak TM, Strizhak AV, Gladysz-Plaska A, Sternik D, Komarov IV, Kolodynska D, Majdan M, Tertykh VA, J. Hazard. Mater., 314, 326 (2016)
  18. Zeng Z, Yang S, Zhang L, Hua D, RSC Adv., 6, 74110 (2016)
  19. Pan XD, Cao JX, Wang YJ, Huang W, Hua DB, Zhu XL, Liang HJ, Polymer, 53(16), 3508 (2012)
  20. Hua DB, Tang J, Jiang JL, Zhu XL, Bai RK, Macromolecules, 42(22), 8697 (2009)
  21. Das S, Oyola Y, Mayes RT, Janke CJ, Kuo LJ, Gill G, Wood JR, Dai S, Ind. Eng. Chem. Res., 55(15), 4103 (2016)
  22. Shao D, Wang X, Wang X, Hu S, Hayat T, Alsaedi A, Li J, Wang S, Hu J, Wang X, RSC Adv., 6, 52076 (2016)
  23. Dong Z, Qiu Y, Dai Y, Cao X, Wang L, Wang P, Lai Z, Zhang W, Zhang Z, Liu Y, Le Z, J. Radioanal. Nucl. Chem., 309, 1217 (2016)
  24. Hu JT, Ma HJ, Xing Z, Liu XY, Xu L, Li R, Lin CJ, Wang MH, Li JY, Wu GZ, Ind. Eng. Chem. Res., 55(15), 4118 (2016)
  25. Chen H, Shao D, Li J, Wang X, J. Chem. Eng., 254, 623 (2014)
  26. Lagaron JM, Lopez-Quintana S, Rodriguez-Cabello JC, Merino JC, Pastor JM, Polymer, 41(8), 2999 (2000)
  27. Romero G, Estrela-Lopis I, Zhou J, Rojas E, Franco A, Espinel CS, Fernandez AG, Gao CY, Donath E, Moya SE, Biomacromolecules, 11(11), 2993 (2010)
  28. Wu D, Shen Y, Ding A, Qiu M, Yang Q, Zheng S, Environ. Technol., 34, 2663 (2013)
  29. Chi F, Wang X, Xiong J, Hu S, J. Radioanal. Nucl. Chem., 296, 1331 (2013)
  30. Siow KS, Britcher L, Kumar S, Griesser HJ, Plasma Process. Polym., 11, 133 (2014)
  31. Li WT, Liu Q, Liu JY, Zhang HS, Li RM, Li ZS, Jing XY, Wang J, Appl. Surf. Sci., 403, 378 (2017)
  32. Tsafack MJ, Levalois-Grqtzmacher J, Surf. Coat. Technol., 200, 3503 (2006)
  33. Kim MJ, Jeon IY, Seo JM, Dai L, Baek JB, AAPG Bull., 8, 2820 (2014)
  34. Joseph P, Tretsiakova-McNally S, Polym. Degrad. Stabil., 97, 2531 (2012)
  35. Puziy AM, Poddubnaya OI, Socha RP, Gurgul J, Wisniewski M, Carbon, 46, 2113 (2008)
  36. Kumar A, Singhal RK, Rout S, Narayanan U, Karpe R, Ravi PM, J. Radioanal. Nucl. Chem., 295, 649 (2013)
  37. Efstathiou M, Pashalidis I, J. Radioanal. Nucl. Chem., 298, 111 (2013)
  38. Endrizzi F, Rao L, J. Chem. Eur., 20, 14499 (2014)
  39. Leggett CJ, Rao L, Polyhedron, 95, 54 (2015)
  40. Endrizzi F, Leggett CJ, Rao LF, Ind. Eng. Chem. Res., 55(15), 4249 (2016)
  41. Tian G, Teat SJ, Rao L, Dalton Trans., 42, 5690 (2013)
  42. Li B, Wang L, Li Y, Wang D, Wen R, Guo X, Li S, Ma L, Tian Y, RSC Adv., 7, 8985 (2017)
  43. Shao D, Hou G, Li J, Wen T, Ren X, Wang X, J. Chem. Eng., 255, 604 (2014)
  44. Shao D, Li J, Wang X, Sci. China Chem., 57, 1449 (2014)
  45. Shao DD, Ren XM, Wen J, Hu S, Xiong J, Jiang T, Wang XL, Wang XK, J. Hazard. Mater., 302, 1 (2016)
  46. Yang P, Liu Q, Liu J, Zhang H, Li Z, Li R, Liu L, Wang J, Ind. Eng. Chem. Res., 56, 3588 (2017)
  47. Yuan L, Liu Y, Shi W, Lv Y, Lan J, Zhao Y, Chai Z, Dalton Trans., 40, 7446 (2011)
  48. Wang X, Yuan L, Wang Y, Li Z, Lan J, Liu Y, Feng Y, Zhao Y, Chai Z, Shi W, Sci. China Chem., 55, 1705 (2012)
  49. Vivero-Escoto JL, Carboni M, Abney CW, deKrafft KE, Lin W, Microporous Mesoporous Mater., 180, 22 (2013)
  50. Xu M, Han X, Hua D, J. Mater. Chem. A, 5, 12278 (2017)
  51. Brown S, Chatterjee S, Li MJ, Yue YF, Tsouris C, Janke CJ, Saito T, Dai S, Ind. Eng. Chem. Res., 55(15), 4130 (2016)
  52. Dong W, Brooks SC, Environ. Sci. Technol., 40, 4689 (2006)
  53. Mehio N, Williamson B, Oyola Y, Mayes RT, Janke C, Brown S, Dai S, Ind. Eng. Chem. Res., 55(15), 4217 (2016)
  54. Tsantis T, Zagoraiou E, Savvidou A, Raptopoulou CP, Psycharis V, Szyrwiel L, Holynska M, Perlepes SP, Dalton Trans., 45, 9307 (2016)
  55. Pang HB, Kuo LJ, Wai CM, Miyamoto N, Joshi R, Wood JR, Strivens JE, Janke CJ, Oyola Y, Das S, Mayes RT, Gill GA, Ind. Eng. Chem. Res., 55(15), 4313 (2016)
  56. Mehio N, Ivanov AS, Ladshaw AP, Dai S, Bryantsev VS, Ind. Eng. Chem. Res., 55(15), 4231 (2016)
  57. Das S, Pandey AK, Athawale A, Kumar V, Bhardwaj Y, Sabharwal S, Manchanda VK, Desalination, 232(1-3), 243 (2008)