pH 감응성 고분자/TiO2/MWCNT 나노컴포지트의 광촉매 분해 특성

임민지; 박지현; 송지은; 김형일; Minji Lim; Jihyun Park; Jieun Song; Hyung-Il Kim

Polymer(Korea), Vol.42, No.6, 1091-1095, November, 2018

DOI10.7317/pk.2018.42.6.1091 Export Citation

pH 감응성 고분자/TiO2/MWCNT 나노컴포지트의 광촉매 분해 특성

Photocatalytic Decomposition Characteristics of pH-Responsive Polymer/TiO2/MWCNT Nanocomposite

임민지, 박지현, 송지은, 김형일^†

충남대학교 응용화학공학과

Minji Lim, Jihyun Park, Jieun Song, and Hyung-Il Kim^†

Department of Chemical Engineering and Applied Chemistry, College of Engineering, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, Korea

E-mail:

초록

TiO2를 광촉매로 사용하고 다중벽 탄소나노튜브(MWCNT)를 전자전달체로 사용하여 폐수정화용 광촉매를 구성하였다. 이를 친수성 폴리비닐알코올(PVA) 및 pH 감응성 폴리아크릴아미드(PAM)로 구성된 하이드로젤에 분산시켜 고분자 나노컴포지트를 제조하였다. PVA/PAM/TiO2/MWCNT 나노컴포지트의 특성을 SEM, XRD, FTIR 및 UV분광분석기를 사용하여 조사하였다. PVA/PAM/TiO2/MWCNT 나노컴포지트에 있어서 MWCNT의 전자전달 효과로 인하여 유기 염료에 대한 광촉매 분해 특성이 현저히 향상되었다.

Photocatalyst for wastewater purification was prepared by using TiO2 as a photocatalyst and MWCNT as an electron transferring additive. Polymer nanocomposite was prepared by dispersing the photocatalyst in the hydrogel consisting of hydrophilic poly(vinyl alcohol) (PVA) and pH-responsive polyacrylamide (PAM). Characteristics of PVA/PAM/ TiO2/MWCNT nanocomposite were investigated by SEM, XRD, FTIR, and UV spectrometer. Electron transferring effect of MWCNT played an important role in the significant improvement of photocatalytic decomposition of organic dye by PVA/PAM/TiO2/MWCNT nanocomposite.

Keywords:photocatalyst;carbon nanotube;pH-responsive hydrogel;nanocomposite

[References]

Yoo HN, Song KG, Lee JS, Choi KJ, Hong SW, J. Hazard. Mater., 258, 124 (2013)
Jung WY, Lee SH, Hong SS, J. Environ. Sci., 4, 511 (2011)
Hoffmann MR, Martin ST, Choi WY, Bahnemann DW, Chem. Rev., 95(1), 69 (1995)
Kominami H, Kato J, Takada Y, Doushi Y, Ohtani B, Nishimoto S, Inoue M, Inui T, Kera Y, Catal. Lett., 46(3-4), 235 (1997)
Huffman AS, Afrassiabi A, Dong LC, J. Control. Release, 4, 213 (1986)
Li YH, Zhu YQ, Zhao YM, Wu DH, Luan ZK, Diamond Relat. Mater., 15, 90 (2006)
Yun CH, Lee HS, Polym. Sci. Technol., 18(1), 4 (2007)
Han JT, Jeong HJ, Lee KW, Electr. Electron. Mater., 22, 29 (2009)
So DS, Kim KH, Lee HS, Seo JH, KIC News, 10, 20 (2007)
Simon-Deckers A, Gouget B, Mayne-L’Hermite M, Herlin-Boime N, Reynaud C, Carriere M, Toxicol., 253, 137 (2008)
Hyung H, Fortner JD, Hughes JB, Kim JH, Environ. Sci. Technol., 41, 179 (2007)
Li YH, Liu FQ, Xia B, Du QJ, Zhang P, Wang DC, Wang ZH, Xia YZ, J. Hazard. Mater., 177(1-3), 876 (2010)
Jang HD, Kim SK, KIC News, 3, 41 (2000)
Scitani A, Palmisano L, Davi E, New J. Chem., 14, 265 (1990)
Park SE, Nho YC, Lim YM, Kim HI, J. Appl. Polym. Sci., 91(1), 636 (2004)
Yun J, Kim HI, J. Ind. Eng. Chem., 15(6), 902 (2009)
Yun J, Im JS, Lee YS, Bae TS, Lim YM, Kim HI, Colloids Surf. A: Physicochem. Eng. Asp., 368, 23 (2010)
Li XH, Niu JL, Zhang J, Li HL, Liu ZF, J. Phys. Chem. B, 107(11), 2453 (2003)

[Referenced By]

[1] Yoo HN, Song KG, Lee JS, Choi KJ, Hong SW, J. Hazard. Mater., 258, 124 (2013)

[2] Jung WY, Lee SH, Hong SS, J. Environ. Sci., 4, 511 (2011)

[3] Hoffmann MR, Martin ST, Choi WY, Bahnemann DW, Chem. Rev., 95(1), 69 (1995)

[4] Kominami H, Kato J, Takada Y, Doushi Y, Ohtani B, Nishimoto S, Inoue M, Inui T, Kera Y, Catal. Lett., 46(3-4), 235 (1997)

[5] Huffman AS, Afrassiabi A, Dong LC, J. Control. Release, 4, 213 (1986)

[6] Li YH, Zhu YQ, Zhao YM, Wu DH, Luan ZK, Diamond Relat. Mater., 15, 90 (2006)

[7] Yun CH, Lee HS, Polym. Sci. Technol., 18(1), 4 (2007)

[8] Han JT, Jeong HJ, Lee KW, Electr. Electron. Mater., 22, 29 (2009)

[9] So DS, Kim KH, Lee HS, Seo JH, KIC News, 10, 20 (2007)

[10] Simon-Deckers A, Gouget B, Mayne-L’Hermite M, Herlin-Boime N, Reynaud C, Carriere M, Toxicol., 253, 137 (2008)

[11] Hyung H, Fortner JD, Hughes JB, Kim JH, Environ. Sci. Technol., 41, 179 (2007)

[12] Li YH, Liu FQ, Xia B, Du QJ, Zhang P, Wang DC, Wang ZH, Xia YZ, J. Hazard. Mater., 177(1-3), 876 (2010)

[13] Jang HD, Kim SK, KIC News, 3, 41 (2000)

[14] Scitani A, Palmisano L, Davi E, New J. Chem., 14, 265 (1990)

[15] Park SE, Nho YC, Lim YM, Kim HI, J. Appl. Polym. Sci., 91(1), 636 (2004)

[16] Yun J, Kim HI, J. Ind. Eng. Chem., 15(6), 902 (2009)

[17] Yun J, Im JS, Lee YS, Bae TS, Lim YM, Kim HI, Colloids Surf. A: Physicochem. Eng. Asp., 368, 23 (2010)

[18] Li XH, Niu JL, Zhang J, Li HL, Liu ZF, J. Phys. Chem. B, 107(11), 2453 (2003)