Journal of Polymer Science Part B: Polymer Physics, Vol.34, No.13, 2223-2229, 1996
Effect of Length and Number of Interlinking Molecules on the Strength of Adhesion
The fracture energy G of an adhesive bond appears to he a product of two terms : G = G(o)[1 + f(R, T)], where G(o) is the intrinsic (chemical) strength of the interface and f(R, T), usually much larger than unity, reflects energy dissipated within the adherends at a crack speed R and temperature T. Values of G(o) have been determined for interlinked sheets of an SBR elastomer by measuring the peel strength at low rates and high temperatures, and in the swollen state, to minimize internal losses. Both the density Delta N and molecular length L of interlinking molecules were varied. G(o) was found to increase in proportion to (Delta N)L(3/2), in accord with the molecular theory of Lake and Thomas. As the peel rate was raised and the test temperature lowered, G was considerably increased by internal dissipative processes, becoming as much as 1000 X G(o) near the glass transition. The loss function f(R, T) was found to depend somewhat upon the strand length L, being about twice as large at intermediate peel rates when L was increased by 40%. It also depended on the density Delta N of interlinking molecules, being about twice as large at high peel rates when the density of interlinks was reduced by a factor of six. Thus, the loss function f(R, T) is greater when the interlinking molecules are few and long, and it is lower when they are many and short. However, it is mainly governed by two parameters : peel rate R and temperature difference (T - T-g), in accord with a viscoelastic loss mechanism.