화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.26, No.11, 965-972, November, 2018
DOI10.1007/s13233-018-6118-9  Export Citation
Poly(vinylidene fluoride)/Plasma-Treated BaTiO3 Nanocomposites with Enhanced Electroactive Phase
Ran Ding1, 2, Lei Gong1, 2, †, Ming-ming Li1, 2, Shu-hua Chen1, 2, Shi-ping Zhan1, 2, Xu-dong Sun1, 2, Cheng Zhang3, 4, and Tao Shao3, 4
  • 1Department of Environment and Chemical Engineering, Dalian University, Dalian, 116622, Liaoning, P. R. China
  • 2Liaoning Engineering Labortory for special optical functional crystals, Dalian University, Dalian, 116622, Liaoning, P. R. China
  • 3Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, P. R. China
  • 4University of Chinese Academy of Sciences, Beijing 100039, P. R. China
E-mail:
Functional C=O and C-O groups are successfully fixated onto the surface of a high dielectric constant material barium titanate (BaTiO3) via non-thermal plasma. The strong dipole interaction exists between these functional groups and CH2 or CF2 groups of poly(vinylidene fluoride) (PVDF), resulting in the enhancement of the electroactive γ-phase of PVDF/BaTiO3 nanocomposites on one hand; on the other hand the dispersion of BaTiO3 is enhanced in the PVDF matrix, where the smaller spherulite size and better hydrophilic property are observed in the PVDF/plasmatreated BaTiO3 nanocomposite, comparing with the untreated ones. Therefore, the PVDF/plasma-treated BaTiO3 nanoparticles exhibited higher dielectric constant and lower dielectric loss than the PVDF/BaTiO3 nanoparticles.
Keywords:poly(vinylidene fluoride) (PVDF);plasma-treated barium titanate nanocomposites;electroactive γ-phase;dielectric constant;dielectric loss
  1. Dang ZM, Yuan JK, Zha JW, Zhou T, Li ST, Hu GH, Prog. Mater. Sci., 57(4), 660 (2012)
  2. Xie L, Huang X, Yang K, Li S, Jiang P, J. Mater. Chem. A, 2, 5244 (2014)
  3. Ramesh S, Shutzberg BA, Huang C, Gao J, IEEE Trans. Adv. Packag., 26, 17 (2003)
  4. Sharma T, Je SS, Gill B, Zhang JXJ, Sens. Actuators A-Phys., 177, 87 (2012)
  5. Huang X, Xie L, Jiang P, Wang G, Liu F, J. Phys. D-Appl. Phys., 42, 245407 (2009)
  6. Sharma M, Madras G, Bose S, Macromolecules, 47, 1392 (2017)
  7. Wu S, Li WP, Lin MR, Burlingame Q, Chen Q, Payzant A, Xiao K, Zhang QM, Adv. Mater., 25(12), 1734 (2013)
  8. Cho S, Lee JS, Jang J, ACS Appl. Mater. Interfaces, 7, 9668 (2015)
  9. Lee BS, Park B, Yang HS, Han JW, Choong C, Bae J, Lee K, Yu WR, Jeong U, Chung UI, ACS Appl. Mater. Interfaces, 6, 3520 (2014)
  10. Tang H, Lin Y, Sodano HA, Adv. Energy Mater., 3, 451 (2013)
  11. Lin MF, Lee PS, J. Mater. Chem. A, 1, 1445 (2013)
  12. Stefanescu EA, Tan XL, Lin ZQ, Bowler N, Kessler MR, Polymer, 52(9), 2016 (2011)
  13. Ke K, Potschke P, Jehnichen D, Fischer D, Voit B, Polymer, 55(2), 611 (2014)
  14. Fabiano S, Crispin X, Berggren M, ACS Appl. Mater. Interfaces, 6, 438 (2014)
  15. Cauda V, Stassi S, Bejtka K, Canavese G, ACS Appl. Mater. Interfaces, 5, 6430 (2013)
  16. Yu K, Wang H, Zhou Y, Bai Y, Niu Y, J. Appl. Phys., 113, 2 (2013)
  17. Krishnamoorti R, MRS Bull., 32, 341 (2007)
  18. Fan YY, Wang GY, Huang XY, Bu J, Sun XJ, Jiang PK, Appl. Surf. Sci., 364, 798 (2016)
  19. Zhou T, Zha JW, Cui RY, Fan BH, Yuan JK, Dang ZM, ACS Appl. Mater. Interfaces, 3, 2184 (2011)
  20. Xie L, Huang X, Huang Y, Yang K, Jiang P, ACS Appl. Mater. Interfaces, 5, 1747 (2013)
  21. Jiang SL, Yu Y, Zeng YK, Curr. Appl. Phys., 9(5), 956 (2009)
  22. Zhao Y, Liu XL, Dou XL, Chen JF, J. Adv. Phys., 4, 357 (2015)
  23. Li Y, Huang X, Hu Z, Jiang P, Li S, Tanaka T, ACS Appl. Mater. Interfaces, 3, 4396 (2011)
  24. Shen Y, Guan Y, Hu Y, Lei Y, Song Y, Lin Y, Nan CW, Appl. Phys. Lett., 103, 1939 (2013)
  25. Yang K, Huang X, Huang Y, Xie L, Jiang P, Chem. Mater., 25, 2327 (2013)
  26. Xie L, Huang X, Wu C, Jiang P, J. Mater. Chem., 21, 5897 (2011)
  27. Geyter ND, Morent R, Leys C, Gengembre L, Payen E, Vlierberghe SV, Schacht E, Surf. Coat. Technol., 202, 3000 (2008)
  28. Zhang C, Zhou Y, Shao T, Xie Q, Xu JY, Yang WJ, Appl. Surf. Sci., 311, 468 (2014)
  29. Zhi F, Hao L, Hao Y, Xie X, Qiu Y, Edmund K, IEEE Trans. Plasma Sci., 255, 7279 (2009)
  30. Morent R, Geyter ND, Leys C, Nucl. Instrum. Methods Phys. Res. Sect. B-Beam Interact. Mater. Atoms, 266, 3081 (2008)
  31. Fang Z, Liu Y, Liu K, Shao T, Zhang C, Vacuum, 86, 1305 (2012)
  32. Fang Z, Ji S, Pan J, Shao T, Zhang C, IEEE Trans. Plasma Sci., 40, 883 (2012)
  33. Jin AK, Dong GS, Kang TJ, Youn JR, Carbon, 44, 1898 (2006)
  34. Long TM, Prakash S, Shannon MA, Moore JS, Langmuir, 22(9), 4104 (2006)
  35. Shao T, Zhang C, Yu Y, Fang Z, Yan P, Europhys. Lett., 97, 55005 (2012)
  36. Bubert H, Haiber S, Brandl W, Marginean G, Heintze M, Bruser V, Diam. Relat. Mater., 12, 811 (2003)
  37. Shao T, Zhang D, Yu Y, Zhang C, Wang J, Yan P, Zhou Y, IEEE Trans. Plasma Sci., 38, 1651 (2010)
  38. Perezmendoza M, Domingogarcia M, Fernandezmorales I, Martinezalonso A, J. Phys. Chem. B, 110, 11327 (2006)
  39. Fang Z, Ruan C, Shao T, Zhang C, Plasma Sources Sci. Technol., 25, 01LT01 (2016)
  40. Wang R, Zhang K, Shen Y, Zhang C, Zhu W, Shao T, Plasma Sources Sci. Technol., 25, 015020 (2016)
  41. Song Y, Shen Y, Liu H, Lin Y, Li M, Nan CW, J. Mater. Chem., 22, 8063 (2012)
  42. Acres RG, Ellis AV, Alvino J, Lenahan CE, Khodakov DA, Metha GF, Andersson GG, J. Phys. Chem. C, 116, 6289 (2012)
  43. Shao T, Zhang C, Long KH, Zhang DD, Wang J, Yan P, Zhou YX, Appl. Surf. Sci., 256(12), 3888 (2010)
  44. Grossiord N, Loos J, Regev O, Koning CE, Chem. Mater., 18, 1089 (2006)
  45. Gong L, Yin B, P L. Li P, Yang MB, Compos. Part B: Eng., 73, 49 (2015)
  46. Ahn Y, Lim JY, Hong SM, Lee J, Ha J, Choi HJ, Seo Y, J. Phys. Chem. C, 117, 11791 (2013)
  47. Manna S, Batabyal SK, Nandi AK, J. Phys. Chem. B, 110(25), 12318 (2006)
  48. Wang D, Bao Y, Zha JW, Zhao J, Dang ZM, Hu GH, ACS Appl. Mater. Interfaces, 4, 6273 (2012)
  49. Balaji PM, Katari V, Ehab A, Gavin L, Hemant G, Salunke AKT, J. Phys. Chem. C, 118, 20819 (2014)
  50. Yang XJ, Li JY, Lei YP, Adv. Mater. Res., 668, 17 (2013)
  51. Theapsak S, Watthanaphanit A, Rujiravanit R, ACS Appl. Mater. Interfaces, 4, 2474 (2012)
  52. Labay C, Canal C, Garcia-Celma MJ, Plasma Chem. Plasma Process., 30(6), 885 (2010)
  53. Riau AK, Mondal D, Yam GHF, Setiawan M, Liedberg B, Venkatraman SS, Mehta JS, ACS Appl. Mater. Interfaces, 7, 21690 (2010)
  54. Bhimasankaram T, Suryanarayana SV, Prasad G, Curr. Sci., 74, 967 (1998)
  55. Mendes SF, Costa CM, Caparros C, Sencadas V, Lanceros-Mendez S, J. Mater. Sci., 47(3), 1378 (2012)
  56. Li Y, Huang X, Hu Z, Jiang P, Li S, Tanaka T, ACS Appl. Mater. Interfaces, 3, 4396 (2011)