화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.68, 109-116, December, 2018
DOI10.1016/j.jiec.2018.07.034  Export Citation
Exploration of structural, thermal and spectroscopic properties of self-activated sulfate Eu2(SO4)3 with isolated SO4 groups
Yu.G. Denisenko1, 2, A.S. Aleksandrovsky3, 4, V.V. Atuchin5, 6, †, A.S. Krylov7, M.S. Molokeev8, 9, A.S. Oreshonkov7, 9, Shestakov7, and O.V. Andreev1
  • 1Institute of Chemistry, Tyumen State University, Tyumen 625003, Russia, Russian Federation
  • 2Department of General and Special Chemistry, Industrial University of Tyumen, Tyumen 625000, Russia, Russian Federation
  • 3Laboratory of Coherent Optics, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia, Russian Federation
  • 4Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk 660041, Russia, Russian Federation
  • 5Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk 630090, Russia, Russian Federation
  • 6Laboratory of Semiconductor and Dielectric Materials, Novosibirsk State University, Novosibirsk 630090, Russia, Russian Federation
  • 7Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia, Russian Federation
  • 8Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia, Russian Federation
  • 9Siberian Federal University, Krasnoyarsk 660041, Russia, Russian Federation
E-mail:
Eu2(SO4)3 was synthesized by chemical precipitation method and the crystal structure was determined by Rietveld analysis. The compound crystallizes in monoclinic space group С2/с. In the air environment, Eu2(SO4)3 is stable up to 670 °C. The sample of Eu2(SO4)3 was examined by Raman, Fourier-transform infrared absorption and luminescence spectroscopy methods. The low site symmetry of SO4 tetrahedra results in the appearance of the IR inactive ν1 mode around 1000 cm-1 and ν2 modes below 500 cm-1. The band intensities redistribution in the luminescent spectra of Eu3+ ions is analyzed in terms of the peculiarities of its local environment.
Keywords:Europium sulfate;Synthesis;Structure;Thermal analysis;Photoluminescence
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