Selective doping of Li-rich layered oxide cathode materials for high-stability rechargeable Li-ion batteries

Dongwook Han; Kwangjin Park; Jun-Ho Park; Dong-Jin Yun; You-Hwan Son

Journal of Industrial and Engineering Chemistry, Vol.68, 180-186, December, 2018

DOI10.1016/j.jiec.2018.07.044 Export Citation

Selective doping of Li-rich layered oxide cathode materials for high-stability rechargeable Li-ion batteries

Dongwook Han¹, Kwangjin Park^{2, †}, Jun-Ho Park^{3, 4}, Dong-Jin Yun⁵, and You-Hwan Son^{3, †}

¹Department of Materials Science and Engineering, Hallym University, 1 Hallymdaehak-gil, Chuncheon, Gangwon-do, 24252, Republic of Korea
²Department of Mechanical Engineering, Gachon University, 1342 Sungnamdaero, Sungnam, Gyeonggi-do, 13120, Republic of Korea
³Energy Lab, Samsung Advanced Institute of Technology, 130 Samsung-ro, Yeongtong-gu, Suwon, Gyeonggi-do, 16678, Republic of Korea
⁴Department of Materials Science and Engineering and Research Institute of Advanced Materials, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul, 08826, Republic of Korea
⁵Analytical Science Lab, Samsung Advanced Institute of Technology, 130 Samsung-ro, Yeongtong-gu, Suwon, Gyeonggi-do, 16678, Republic of Korea

E-mail:,

We report the discovery of Li-rich Li1+x[(Ni0.225Co0.15Mn0.625)1-yVy]O2 as a cathode material for rechargeable lithium-ion batteries in which a small amount of tetravalent vanadium (V4+) is selectively and completely incorporated into the manganese sites in the lattice structure. The unwanted oxidation of vanadium to form a V2O5-like secondary phase during high-temperature crystallization is prevented by uniformly dispersing the vanadium ions in coprecipitated [(Ni0.225Co0.15Mn0.625)1?yVy](OH)2 particles. Upon doping with V4+ ions, the initial discharge capacity (>275 mA h g-1), capacity retention, and voltage decay characteristics of the Li-rich layered oxides are improved significantly in comparison with those of the conventional undoped counterpart.

Keywords:Lithium-rich layered oxide;Vanadium ion;Coprecipitation;Selective doping site;Rechargeable lithium-ion batteries

[References]

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Kong F, Longo RC, Park MS, Yoon J, Yeon DH, Park JH, Wang WH, Kc S, Doo SG, Cho K, J. Mater. Chem. A, 3, 8489 (2015)
Jarvis KA, Deng Z, Allard LF, Manthiram A, Ferreira PJ, Chem. Mater., 23, 3614 (2011)
Kim JH, Park CW, Sun YK, Solid State Ion., 164(1-2), 43 (2003)
Lu C, Yang SQ, Wu H, Zhang Y, Yang XJ, Liang TH, Electrochim. Acta, 209, 448 (2016)
Zhu HL, Xie T, Chen ZY, Li LJ, Xu M, Wang WH, Lai YQ, Li J, Electrochim. Acta, 135, 77 (2014)
Gao J, Kim J, Manthiram A, Electrochem. Commun., 11, 84 (2009)
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[Referenced By]

[1] Armand M, Tarascon JM, Nature, 451, 652 (2008)

[2] Dunn B, Kamath H, Tarascon JM, Science, 334(6058), 928 (2011)

[3] Goodenough JB, Kim Y, Chem. Mater., 22, 587 (2010)

[4] Yang H, Amiruddin S, Bang HJ, Sun YK, Prakash J, J. Ind. Eng. Chem., 12(1), 12 (2006)

[5] Sun K, Peng C, Li Z, Xiao Q, Lei G, Xiao Q, Ding Y, Hu Z, RSC Adv., 6, 28729 (2016)

[6] Zheng Z, Wu Z, Zhong Y, Shen CH, Hua W, Xu BB, Yu C, Zhong BH, Guo XD, RSC Adv., 5, 37330 (2015)

[7] Cho Y, Oh P, Cho J, Nano Lett., 13, 1145 (2013)

[8] Manthiram A, Knight JC, Myung ST, Oh SM, Sun YK, Adv. Energy Mater., 6, 150101 (2016)

[9] Zheng Z, Hua WB, Yu C, Xu BB, Wang JZ, Zhong BH, Zhang ZY, Dalton Trans., 44, 14255 (2015)

[10] Yan J, Liu X, Li B, RSC Adv., 4, 63268 (2014)

[11] Ko YN, Kim JH, Lee JK, Kang YC, Lee JH, Electrochim. Acta, 69, 345 (2012)

[12] Sha O, Tang ZY, Wang SL, Yuan W, Qiao Z, Xu Q, Ma L, Electrochim. Acta, 77, 250 (2012)

[13] Song BH, Lai MO, Lu L, Electrochim. Acta, 80, 187 (2012)

[14] Hao LF, Zhang M, Yuan HT, Zhao M, Guo H, Wang W, Di Zhou X, Wang YM, J. Power Sources, 167(1), 178 (2007)

[15] Park SH, Sun YK, J. Power Sources, 119, 161 (2003)

[16] Tabuchi M, Nabeshima Y, Takeuchi T, Kageyama H, Imaizumi J, Shibuya H, Akimoto J, J. Power Sources, 221, 427 (2013)

[17] Tabuchi M, Nabeshima Y, Takeuchi T, Kageyama H, Tatsumi K, Akimoto J, Shibuya H, Imaizumi J, J. Power Sources, 196(7), 3611 (2011)

[18] Tang ZH, Wang ZX, Li XH, Peng WJ, J. Power Sources, 204, 187 (2012)

[19] Kong F, Longo RC, Park MS, Yoon J, Yeon DH, Park JH, Wang WH, Kc S, Doo SG, Cho K, J. Mater. Chem. A, 3, 8489 (2015)

[20] Jarvis KA, Deng Z, Allard LF, Manthiram A, Ferreira PJ, Chem. Mater., 23, 3614 (2011)

[21] Kim JH, Park CW, Sun YK, Solid State Ion., 164(1-2), 43 (2003)

[22] Lu C, Yang SQ, Wu H, Zhang Y, Yang XJ, Liang TH, Electrochim. Acta, 209, 448 (2016)

[23] Zhu HL, Xie T, Chen ZY, Li LJ, Xu M, Wang WH, Lai YQ, Li J, Electrochim. Acta, 135, 77 (2014)

[24] Gao J, Kim J, Manthiram A, Electrochem. Commun., 11, 84 (2009)

[25] Boulineau A, Simonin L, Colin JF, Canevet E, Daniel L, Patoux S, Chem. Mater., 24, 3558 (2012)