화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.68, 406-415, December, 2018
DOI10.1016/j.jiec.2018.08.016  Export Citation
Implementation of magnetic Fe3O4@ZIF-8 nanocomposite to activate sodium percarbonate for highly effective degradation of organic compound in aqueous solution
Saeed Sajjadi1, Alireza Khataee1, 2, †, Reza Darvishi Cheshmeh Soltani3, Nafiseh Bagheri1, Afzal Karimi4, and Amirali Ebadi Fard Azar5
  • 1arch Laboratory of Advanced Water and Wastewater Treatment Processes, Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, 51666-16471 Tabriz, Iran
  • 2Department of Materials Science and Nanotechnology Engineering, Faculty of Engineering, Near East University, 99138 Nicosia, North Cyprus, Mersin 10, Turkey
  • 3Department of Environmental Health Engineering, School of Health, Arak University of Medical Sciences, Arak, Iran
  • 4Faculty of Advanced Technologies in Medicine, Iran University of Medical Sciences, 14496-14535 Tehran, Iran
  • 5Faculty of Medicine, Iran University of Medical Sciences, 14496-14535 Tehran, Iran
E-mail:
Here, as-synthesized Fe3O4 nanoparticles were incorporated into the zeolitic imidazolate framework (ZIF-8) lattice to activate sodium percarbonate (SPC) for degradation of methylene blue (MB). The reaction rate constant of Fe3O4@ZIF-8/SPC process (0.0632 min-1) at acidic conditions (pH = 3) was more than six times that of the Fe3O4/SPC system (0.009 min-1). Decreasing the solute concentration, along with increasing SPC concentration and Fe3O4@ZIF-8 nanocomposite (NC) dosage, favored the catalytic degradation of MB. The Fe3O4@ZIF-8 NC after fifteen consecutive treatment processes showed the excellent stability with a negligible drop in the efficiency of the system (<10%). The reaction pathway was obtained via GC-MS analysis.
Keywords:Chemical oxidation;Zeolitic imidazolate framework;Magnetite nanostructures;Textile dye;Solid hydrogen peroxide
  1. Thines RK, Mubarak NM, Nizamuddin S, Sahu JN, Abdullah EC, Ganesan P, J. Taiwan Inst. Chem. Eng., 72, 116 (2017)
  2. Jorfi S, Soltani RDC, Ahmadi M, Khataee A, Safari M, J. Environ. Manage., 187, 111 (2017)
  3. Hassani A, Soltani RDC, Kiransan M, Karaca S, Karaca C, Khataee A, Korean J. Chem. Eng., 33(1), 178 (2016)
  4. Soltani RDC, Safari M, Mashayekhi M, Ultrason. Sonochem., 30, 123 (2016)
  5. Jin G, Eom Y, Lee TG, J. Ind. Eng. Chem., 42, 46 (2016)
  6. Iritani E, Katagiri N, Yamaoka Y, J. Taiwan Inst. Chem. Eng. (2017), doi:http://dx.doi.org/10.1016/j.jtice.2017.09.040 (in press).
  7. Kim HH, Lee TG, J. Ind. Eng. Chem., 47, 446 (2017)
  8. Fu XR, Gu XG, Lu SG, Sharma VK, Brusseau ML, Xue YF, Danish M, Fu GY, Qiu ZF, Sui Q, Chem. Eng. J., 309, 22 (2017)
  9. Soltani RDC, Rezaee A, Khataee A, Godini H, Res. Chem. Intermed., 39, 4277 (2013)
  10. Lee DW, Yoo BR, J. Ind. Eng. Chem., 20(6), 3947 (2014)
  11. Cho JH, Eom Y, Jeon SH, Lee TG, J. Ind. Eng. Chem., 19(1), 144 (2013)
  12. Miao Z, Gu X, Lu S, Zang X, Wu X, Xu M, Ndong LBB, Qiu Z, Qui Z, Sui Q, Fu GY, Chemosphere, 119, 1120 (2015)
  13. Miao ZW, Gu XG, Lu SG, Brusseau ML, Zhang X, Fu XR, Danish M, Qiu ZF, Sui Q, Chem. Eng. J., 281, 286 (2015)
  14. Acisli Q, Khataee A, Soltani RDC, Karaca S, Ultrason. Sonochem., 35, 210 (2017)
  15. Fu XR, Gu XG, Lu SG, Miao ZW, Xu MH, Zhang X, Qiu ZF, Sui Q, Chem. Eng. J., 267, 25 (2015)
  16. Nakashima K, Ebi Y, Kubo M, Shibasaki-Kitakawa N, Yonemoto T, Ultrason. Sonochem., 29, 455 (2016)
  17. Miao ZW, Gu XG, Lu SG, Brusseau ML, Yan N, Qiu ZF, Sui Q, J. Hazard. Mater., 300, 530 (2015)
  18. Babaei AA, Ghanbari F, J. Water Reuse Desalin., 6(4), 484 (2016)
  19. Sindelar HR, Brown MT, Boyer TH, Chemosphere, 105, 112 (2014)
  20. Huong PTL, Huy LT, Lan H, Thang LH, An TT, Van Quy N, Tuan PA, Alonso J, Phan MH, Le AT, J. Alloy. Compd., 739, 139 (2018)
  21. Li XH, Guo WL, Liu ZH, Wang RQ, Liu H, Appl. Surf. Sci., 369, 130 (2016)
  22. Sharma VK, Feng M, J. Hazard. Mater. (2017), doi:http://dx.doi.org/10.1016/j.jhazmat.2017.09.043 (in press).
  23. Yang N, Ning P, Li K, Wang J, J. Taiwan Inst. Chem. Eng., 86, 73 (2018)
  24. Kumar P, Bansal V, Kim KH, Kwon EE, J. Ind. Eng. Chem., 62, 130 (2018)
  25. Li WH, Wu XF, Li SD, Tang W, Chen YF, Appl. Surf. Sci., 436, 252 (2018)
  26. Ma WJ, Wang N, Fan YA, Tong TZ, Han XJ, Du YC, Chem. Eng. J., 336, 721 (2018)
  27. Ding S, Zhang C, Liu Y, Jiang H, Xing W, Chen R, J. Ind. Eng. Chem., 46, 258 (2017)
  28. Bao Q, Lou Y, Xing T, Chen J, Inorg. Chem. Commun., 37, 170 (2013)
  29. Lin KYA, Chang HA, J. Taiwan Inst. Chem. Eng., 53, 40 (2015)
  30. Kong RM, Zhao Y, Zheng Y, Qu F, RSC Adv., 7, 31365 (2017)
  31. Jiang X, Chen HY, Liu LL, Qiu LG, Jiang X, J. Alloy. Compd., 646, 1075 (2015)
  32. Farzi-Khajeh H, Safa KD, Dastmalchi S, J. Chromatogr. B, 1068-10, 210 (2017)
  33. Pan Y, Liu Y, Zeng G, Zhao L, Lai Z, Chem. Commun., 47, 2071 (2011)
  34. Fu XR, Gu XG, Lu SG, Sharma VK, Brusseau ML, Xue YF, Danish M, Fu GY, Qiu ZF, Sui Q, Chem. Eng. J., 309, 22 (2017)
  35. Cui H, Gu XG, Lu SG, Fu XR, Zhang X, Fu GY, Qiu ZF, Sui Q, Chem. Eng. J., 309, 80 (2017)
  36. Khataee A, Sheydaei M, Hassani A, Taseidifar M, Karaca S, Ultrason. Sonochem., 22, 404 (2015)
  37. Khataee A, Sajjadi S, Hasanzadeh A, Vahid B, Joo SW, J. Environ. Manage., 199, 31 (2017)
  38. Lu Y, Liang X, Niyungeko C, Zhou J, Xu J, Tian G, Talanta, 178, 324 (2018)
  39. Soltani RDC, Mashayekhi M, Chemosphere, 194, 471 (2018)
  40. Jiang H, Sun Y, Feng J, Wang J, Water Sci. Technol., 74, 1116 (2016)
  41. Shao YM, Zhou LC, Bao C, Ma JJ, Liu MZ, Wang F, Chem. Eng. J., 283, 1127 (2016)
  42. Hassani A, Soltani RDC, Karaca S, Khataee A, J. Ind. Eng. Chem., 21, 1197 (2015)
  43. Dadfarnia S, Shabani AMH, Moradi SE, Emami S, Appl. Surf. Sci., 330, 85 (2012)
  44. Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, Sing KS, Pure Appl. Chem., 87, 1051 (2015)
  45. Ahmed I, Bhadra BN, Lee HJ, Jhung SH, Catal. Today, 301, 90 (2018)
  46. Zhu XH, Yang CX, Yan XP, Microporous Mesoporous Mater., 259, 163 (2018)
  47. Sze MFF, McKay G, Environ. Pollut., 158, 1669 (2010)
  48. Cui H, Gu XG, Lu SG, Fu XR, Zhang X, Fu GY, Qiu ZF, Sui Q, Chem. Eng. J., 309, 80 (2017)
  49. Soltani RDC, Jorfi S, Safari M, Rajaei MS, J. Environ. Manage., 179, 47 (2016)
  50. U.S.EPA . National Secondary Drinking Water Regulations (NSDWRs) U.S.E.P. Agency , 2009;.