The conversion of bio-char to CaC2 is a potential way to achieve the production of high-value-added chemicals from biomass. The unique properties of bio-char, such as its fine particles, high activity, and low ash content, provide a high reaction rate, low reaction temperature, and high CaC2 purity, which increase the feasibility of converting bio-char to CaC2. This work investigates the morphological behaviors of the solid reactants and the products, as well as the reaction kinetics, in terms of changes in activation energy and the particle size of the reactants. The experiments were carried out using a thermal gravimetric analyzer coupled with a mass spectrometer (TG-MS) at temperatures lower than 1700 degrees C using corncob char and CaO as the starting materials. The TG-MS data and kinetics modeling show that at temperatures of 1400-1700 degrees C, the reaction of corncob char and CaO with a particle size of 22-114 mu m is predominantly under reaction control, but is slightly affected by the size of the reactants. During the course of the reaction, the reacting solids agglomerate via the formation of CaC2 without apparent melting. (C) 2018 Elsevier Ltd. All rights reserved.