Journal of Polymer Science Part B: Polymer Physics, Vol.37, No.1, 51-60, 1999
Structural heterogeneity and dynamic mechanical relaxations of ethylene alpha-olefin copolymers
Dynamic mechanical measurements are reported on two polyethylene copolymers with different types of comonomers and well;characterized comonomer distributions. Measurements on both isotropic and oriented samples were undertaken over a wide frequency range. The mechanical anisotropy and activation energies of the alpha and beta relaxations are consistent with the former relating to c-shear in the crystals, and the latter to interlamellar shear.