화학공학소재연구정보센터
Fuel Processing Technology, Vol.180, 67-74, 2018
A two-step process for sewage sludge treatment: Hydrothermal treatment of sludge and catalytic hydrothermal gasification of its derived liquid
The worldwide increase in amount of sewage sludge has recently attracted considerable interest in developing an efficient and economical sludge disposal method. A sewage sludge treatment process combining the hydro thermal treatment (HT) of sludge and the catalytic hydrothermal gasification (CHTG) of its derived liquid (HT& CHTG-Process) is proposed in this paper. Liquid hourly space velocity (LHSV) value of 25-100 h(-1) and liquid flow rate of 10-40 mL/min were employed with a self-designed CHTG experimental setup. During the first stage of the HT-Process, approximately 56% of the carbon in the sludge was transferred into the derived liquid at 300 degrees C, During the second stage of the CHTG-Process, the derived liquid was gasified into CH4, H-2, and CO2 using a Ni/carbon catalyst, and the carbon conversion reached 88% at 350 degrees C and 20 MPa with a LHSV of 25 h(-1). Using the integrated HT&CHGT-Process, approximately 0.78 Nm(3) of CH4, 0.62 Nm(3) of H-2 and 0.31 Nm(3) of CO2 were generated from 1 kg of carbon in the sewage sludge. The combined process was expected to be an efficient method for sewage sludge treatment due to its mild conditions <= 350 degrees C and <= 20 MPa) and high yield of fuel gases.