Materials Chemistry and Physics, Vol.216, 349-353, 2018
Mossbauer spectroscopy and magnetometry of FeCo-Ag and FeCo-Au nanocomposites synthesized by a redox-transmetalation method
Composite nanoparticles (NPs) of FeCo-Ag and FeCo-Au fabricated by the redox-transmetalation technique are characterized by transmission electron microscopy (TEM), X-ray diffractometry (XRD), Mossbauer spectroscopy and magnetometry. TEM images prove the formation of agglomerated quasi-spherical NPs with mean value of diameter < D > about 28 run. As indicated by XRD and Mossbauer spectroscopy composite NPs constitute cores containing Fe3+ Co-based oxides with smaller contribution of bcc alpha-FeCo alloy and shells representing well crystallized Ag and Au. Mean value of diameters < 1) > of magnetic cores (approximate to 10 nm) and non-magnetic shells (approximate to 18 nm) in composite NPs are estimated by complementary analysis of TEM images, broadening of XRD reflections and approximation of hysteresis curves M(H) with Langevin function.
Keywords:Nanostructures;Composite materials;Magnetic structures;Electron microscopy;Mossbauer spectroscopy;Magnetometer