Journal of Rheology, Vol.42, No.1, 215-217, 1998
Intrinsic dynamic viscosity obtained without phase angle data
Dilute-solution data on amplitude ratio and phase difference of stress and strain in sinusoidal shear testing are normally converted first to dynamic viscosity eta'(c) and to eta "(c), where c is mass concentration of solute, and then extrapolated as c --> 0 to obtain the intrinsic values [eta'] and [eta "]. The major source of error is usually measurement of phase angle, while amplitude ratio is more accurately determined. Here, it is shown that [eta'] can be obtained from amplitude ratio alone, and also [eta "] from phase angle alone. Improved accuracy in obtaining [eta'] is thereby possible with this new method of data analysis.