Solar availability on urban facades varies significantly, affected by obstructions by nearby buildings as well as orientation. A convenient way to evaluate their solar energy potential is deemed to facilitate the task of architects in increasing the use of photovoltaic systems and, thus solar energy generation in the urban environment. This study explores to what extent the sky view factor (SVF), a measure of the openness of a point to the sky, can be employed for evaluating solar irradiation of facades in complex urban scenes. For this purpose, extensive statistical analysis was performed testing the correlation of SVF with solar irradiances for 30 orientations, considering three European climates (i.e. Athens, London and Helsinki), and three periods (i.e. year, January and July). Special emphasis is put on global irradiance, which expresses the sum of three solar components, i.e. direct, diffuse and reflected. The study uses 24 urban forms - of 500 x 500 m area - in London for which SVF and solar irradiance simulations were performed for nine sky models (three locations by three periods). The results reveal a strong linear relationship (R-2 > 0.8) between SVF and annual global irradiance in all orientations, at all three locations. In fact, as SVF was found to correlate well with both major solar components, direct and diffuse, it can be presumably used for predicting facades' annual solar irradiation at any location within the tested range of latitudes. With respect to monthly global irradiance, the relationship appears less consistent, affected by the increased sensitivity of the relationship of SVF with monthly direct irradiance to facade orientation and location's latitude, associated with the variations of solar altitude.