화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.69, 304-314, January, 2019
DOI10.1016/j.jiec.2018.09.009  Export Citation
Production of phenolic hydrocarbons from organosolv lignin and lignocellulose feedstocks of hardwood, softwood, grass and agricultural waste
Deokwon Son1, 2, Sangseo Gu1, 2, Jae-Wook Choi1, Dong Jin Suh1, 3, Jungho Jae1, 4, Jungkyu Choi2, and Jeong-Myeong Ha1, 3, †
  • 1Clean Energy Research Center, Korea Institute of Science and Technology, Seoul 02792, Republic of Korea
  • 2Department of Chemical & Biological Engineering, Korea University, Seoul 02841, Republic of Korea
  • 3Green School (Graduate School of Energy and Environment), Korea University, Seoul 02841, Republic of Korea
  • 4Division of Energy & Environment Technology, KIST School, Korea University of Science and Technology, Seoul 02792, Republic of Korea
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Organosolv lignin extracted from the four representative lignocellulose feeds of oil palm empty fruit bunch (agricultural waste), oak (hardwood), pine (softwood) and Miscanthus giganteus (grass) is depolymerized using Ru/H-zeolite β to produce phenolic hydrocarbons. The bulky methoxy functionality, which is rich in oak and pine, sterically hindered the ether bonds, decreasing the yields of phenolic monomers and improving the β-β coupling to repolymerize lignin fragments. Both depolymerization and repolymerization are improved at a higher reaction temperature. The structures and the reaction behavior of organosolv lignin are observed using NMR, GPC, N2-physisorption, SEM and DLS analysis methods.
Keywords:Biofuel;Lignin;Depolymerization;Phenolic hydrocarbons;Ru/Hβ
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