Studies on the Change of Lithium Ion Battery Performance According to Length and Type of Surfactant on the Surface of Manganese Oxide Nanoparticles Prepared by Reverse Micelle Method

Bumkyo Park; Jaemin Kim; Jae Young Lee; Suk Ho Bhang; Junyoung Mun; Taekyung Yu

Macromolecular Research, Vol.26, No.12, 1167-1172, December, 2018

DOI10.1007/s13233-018-6147-4 Export Citation

Studies on the Change of Lithium Ion Battery Performance According to Length and Type of Surfactant on the Surface of Manganese Oxide Nanoparticles Prepared by Reverse Micelle Method

Bumkyo Park, Jaemin Kim¹, Jae Young Lee, Suk Ho Bhang², Junyoung Mun^{1, †}, and Taekyung Yu^†

Department of Chemical Engineering, Kyung Hee University, Yongin 17104, Korea
¹Department of Energy and Chemical Engineering, Innovation Center for Chemical Engineering, Incheon National University, Incheon 22012, Korea
²School of Chemical Engineering, Sungkyunkwan University, Suwon 16419, Korea

E-mail:,

In order to accurately analyze how the surfactant attached on the surface of the nanoparticles affects the catalytic activity, all other experimental conditions should be maintained except the surfactant. In this study, we control the hydrocarbon chain length of the alkylamine and carboxylic acid on the surface of manganese oxide (Mn3O4) nanoparticles while keeping their size and shape using a reverse micelle method. Despite the use of various lengths of surfactants, the size and shape of the synthesized nanoparticles remain virtually unchanged. After the mild heattreatment, they have different secondary particle morphologies even though the nano particles are preserved. Those prepared nanoparticles exhibit the characteristics voltage behavior under the galvanostatic charge and discharge. The obtained electrochemical performances are influenced by the surfactants. A coin cell having Mn3O4 nanoparticles coated by hexanoic acid and hexylamine shows the highest capacity than the other samples.

Keywords:manganese oxide;nanoparticles;reverse micelle;alkylamine;carboxylic acid

[References]

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Park J, Joo J, Kwon S, Jang Y, Hyeon T, Angew. Chem.-Int. Edit., 46, 4630 (2007)
Lee Y, Lee J, Bae CJ, Park JG, Noh HJ, Park JH, Hyeon T, Adv. Funct. Mater., 15(3), 503 (2005)
Pileni MP, Nat. Mater., 2(3), 145 (2003)
Lin J, Lin Y, Liu P, Meziani MJ, Allard LF, Sun YP, J. Am. Chem. Soc., 124(38), 11514 (2002)
Tartaj P, Serna C, J. Chem. Mater., 14, 4396 (2002)
Zhou Z, Wang J, Liu X, Chan H, J. Mater. Chem., 11, 1704 (2001)
Liu C, Zou BS, Rondinone AJ, Zhang ZJ, J. Phys. Chem. B, 104(6), 1141 (2000)
Ngo AT, Pileni MP, Adv. Mater., 12(4), 276 (2000)
Dresco PA, Zaitsev VS, Gambino RJ, Chu B, Langmuir, 15(6), 1945 (1999)
Sun HH, Manthiram A, Chem. Mater., 29, 8486 (2017)
Kim J, Kang H, Go N, Jeong S, Yim T, Jo YN, Lee KT, Mun J, J. Mater. Chem. A, 5, 24892 (2017)
Mun J, Park JH, Choi W, Benayad A, Park JH, Lee JM, Doo SG, Oh SM, J. Mater. Chem. A, 2, 19670 (2014)
Yu BC, Hwa Y, Kim JH, Sohn HJ, J. Power Sources, 260, 174 (2014)
Wang YX, Yang J, Chou SL, Liu HK, Zhang WX, Zhao D, Dou SX, Nat. Commun., 6, 8689 (2015)
Guan C, Li X, Yu H, Mao L, Wong LH, Yan Q, Wang J, Nanoscale, 6, 13824 (2014)
Park GD, Lee JK, Kang YC, Adv. Funct. Mater., 27, 160339 (2017)
Jadhav HS, Thorat GM, Mun J, Seo JG, J. Power Sources, 302, 13 (2016)
Yu T, Moon J, Park J, Park YI, Na HB, Kim BH, Song IC, Moon WK, Hyeon T, Chem. Mater., 21, 2272 (2009)
Wang HL, Cui LF, Yang YA, Casalongue HS, Robinson JT, Liang YY, Cui Y, Dai HJ, J. Am. Chem. Soc., 132(40), 13978 (2010)
Zhuang Y, Ma Z, Deng Y, Song X, Zuo X, Xiao X, Nan J, Electrochim. Acta, 245, 448 (2017)
Wang MY, Huang Y, Zhang N, Wang K, Chen XF, Ding X, Chem. Eng. J., 334, 2383 (2018)

[Referenced By]

[1] Lee H, Habas S, Kweskin S, Butcher D, Somorjai G, Yang P, Angew. Chem.-Int. Edit., 45, 7864 (2006)

[2] Park J, Joo J, Kwon S, Jang Y, Hyeon T, Angew. Chem.-Int. Edit., 46, 4630 (2007)

[3] Lee Y, Lee J, Bae CJ, Park JG, Noh HJ, Park JH, Hyeon T, Adv. Funct. Mater., 15(3), 503 (2005)

[4] Pileni MP, Nat. Mater., 2(3), 145 (2003)

[5] Lin J, Lin Y, Liu P, Meziani MJ, Allard LF, Sun YP, J. Am. Chem. Soc., 124(38), 11514 (2002)

[6] Tartaj P, Serna C, J. Chem. Mater., 14, 4396 (2002)

[7] Zhou Z, Wang J, Liu X, Chan H, J. Mater. Chem., 11, 1704 (2001)

[8] Liu C, Zou BS, Rondinone AJ, Zhang ZJ, J. Phys. Chem. B, 104(6), 1141 (2000)

[9] Ngo AT, Pileni MP, Adv. Mater., 12(4), 276 (2000)

[10] Dresco PA, Zaitsev VS, Gambino RJ, Chu B, Langmuir, 15(6), 1945 (1999)

[11] Sun HH, Manthiram A, Chem. Mater., 29, 8486 (2017)

[12] Kim J, Kang H, Go N, Jeong S, Yim T, Jo YN, Lee KT, Mun J, J. Mater. Chem. A, 5, 24892 (2017)

[13] Mun J, Park JH, Choi W, Benayad A, Park JH, Lee JM, Doo SG, Oh SM, J. Mater. Chem. A, 2, 19670 (2014)

[14] Yu BC, Hwa Y, Kim JH, Sohn HJ, J. Power Sources, 260, 174 (2014)

[15] Wang YX, Yang J, Chou SL, Liu HK, Zhang WX, Zhao D, Dou SX, Nat. Commun., 6, 8689 (2015)

[16] Guan C, Li X, Yu H, Mao L, Wong LH, Yan Q, Wang J, Nanoscale, 6, 13824 (2014)

[17] Park GD, Lee JK, Kang YC, Adv. Funct. Mater., 27, 160339 (2017)

[18] Jadhav HS, Thorat GM, Mun J, Seo JG, J. Power Sources, 302, 13 (2016)

[19] Yu T, Moon J, Park J, Park YI, Na HB, Kim BH, Song IC, Moon WK, Hyeon T, Chem. Mater., 21, 2272 (2009)

[20] Wang HL, Cui LF, Yang YA, Casalongue HS, Robinson JT, Liang YY, Cui Y, Dai HJ, J. Am. Chem. Soc., 132(40), 13978 (2010)

[21] Zhuang Y, Ma Z, Deng Y, Song X, Zuo X, Xiao X, Nan J, Electrochim. Acta, 245, 448 (2017)

[22] Wang MY, Huang Y, Zhang N, Wang K, Chen XF, Ding X, Chem. Eng. J., 334, 2383 (2018)