화학공학소재연구정보센터
Applied Chemistry for Engineering, Vol.29, No.6, 753-758, December, 2018
람노리피드의 계면특성 및 액체세정제에서의 기능에 대한 연구
Study on the Surface Activity of Rhamnolipid (RL) and Function of RL in Liquid Detergent
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초록
미생물 발효 생계면활성제인 람노리피드의 계면활성(CMC, 표면장력, 기포력 등)을 측정하였다. 람노리피드는 우수한 표면활성을 나타내었다. 람노리피드가 처방된 세정제도 우수한 표면활성을 나타내었다. 액체세정제의 성능평가 결과 지방산 대비 람노리피드가 사용된 제품의 성능이 미세하게 우세하였다. 그렇지만 기포 프로화일에서는 람노리피드가 처방된 제품의 기포량이 아주 많았으며, 헹굼과정에서 지방산의 억포작용과 같은 헹굼성 보조 작용은 나타나지 않았다. 람노리피드는 생계면활성제로써 주계면활성제 또는 보조계면활성제로써 사용될 수 있을 것이다. 그러나 지방산과 같은 억포제 또는 헹굼 보조 기능은 가지지 않은 것으로 판단된다.
Surface activities including CMC, surface tension, foaming power etc. of the rhamnolipid (RL), a biosurfactant fermented by microorganism were investigated. Both the RL and liquid detergent contained RL showed a good surface activity. For the detergency test, the liquid detergent with RL showed a slightly better performance than that of using an fatty acid. However for the foaming profile, the liquid detergent with RL exhibited a lot of foam volume and the suppression of the rinsing and foaming during rinsing cycles with the RL was not seen. Therefore it can be concluded that RL can be used as a main surfactant or co-surfactant in liquid detergents without functions of foaming suppression or rinse-aid.
  1. Kang YS, Theory and Technology of Laundry Detergent, 1st ed. 51-57, Yewonsa, Korea (2005).
  2. Santos DK, Rufino RD, Luna JM, Santos VA, Sarubbo LA, Int. J. Mol. Sci., 17(3), 401 (2016)
  3. Lee MJ, Park BD, Lee ST, Kim MG, New Tetragenococcus koreensis producing rhamnolipid and production method of rhamnolipid using this Tetragenococcus koreensis, Korean Patent, 2007-0027151 (2005).
  4. Nataforeun L, Danny D, Preparation of rhamnolipid composition, Korean Patent, 2017-0102903 (2016).
  5. Kong JY, Pseudomonas aeruginosa, Korean Patent, 10-0018783 (2004).
  6. Chae MS, Pseudomonas aeruginosa, Korean Patent, 10-0038285 (1999).
  7. Kim HY, Pseudomonas aeruginosa, Korean Patent, 10-2016-0077818 (2014).
  8. De Rienzo MAD, Kamalanathan ID, Martin PJ, Process Biochem., 51(7), 820 (2016)
  9. Lee KM, Hwang SH, Ha SD, Jang JH, Lim DJ, Kong JY, Biotechnol. Bioprocess Eng., 9(4), 267 (2004)
  10. Kim EG, Red tide prevention method using rhamnolipid, Korean Patent, 10-0384284 (2000).
  11. Kim IS, Chae DH, Kim SG, Pseudomonas, Korean Patent, 10-0940231 (2009).
  12. Kim IS, Kim RH, Composition contained rhamnolipid which preveting biofilm forming and method suppressing biofilm forming, Korean Patent, 10-1651170 (2014).
  13. hwang BK, Kim BS, Moon SS, Pseudomonas aeruginosa, Korean Patent, 10-2001-0038285 (1999).
  14. Choi SH, Park GI, Pseudomonas aeruginosa, Korean Patent, 10-1633888 (2014).
  15. Magalhaes L, Nitschke M, Food Control, 29, 138 (2013)
  16. Dusane DH, Nancharaiah YV, Zinjarde SS, Venugopalan VP, Colloids Surf. B: Biointerfaces, 81, 242 (2010)
  17. Denyer SP, Maillard JY, J. Appl. Microbiol., 92, 35S (2002)
  18. DeSanto K, Rhamnolipid-based formulations, US Patents, US 8,183,198 B2 (2012).
  19. Lee CW, Light-duty liquid detergent minimizing the damage of fabric and skin, Korean Patent, 1997-0002048 (1994).
  20. Jang GH, Kang CS, Kim JH, Transparent body cleanser composition, Korean Patent, 1999-0066544 (1998).
  21. Cho GH, Lee SY, Maeng WH, Detergent composition which is good solubility and rinsing, Korean Patent, 10-0458234 (2002).
  22. Cho IS, Chi GY, Kim HS, Nam GC, Lee GJ, Liquid detergent composition which is for permeability and repellant materials, Korean Patent, 10-2010-0042803 (2008).
  23. Yosiyuki H, Hirotsuku O, Misa H, Hiroaki S, Takesi T, Liquid detergent composition which is for detergency and fabric products, Korean Patent, 10-2014-0078664 (2012).
  24. Mitsutosi M, Hatsuki T, Liquid detergent composition, Korean Patent, 10-1876272 (2013).
  25. Junko N, Tosihiko T, Granule detergent and detergent product, Korean Patent, 10-2017-0061657 (2015).
  26. Kang YS, Gyeong KY, Rang MJ, Bae DH, Lee YG, Cho WG, Choi SK, Han SG, Cosmetic and Household Science 2, 1st ed. 163, Sinkwang Publisher, Korea (2008).
  27. Yosiyuki H, Hirotsuku O, Misa H, Hiroaki S, Takesi T, Liquid detergent composition which is for detergency and fabric products, Korean Patent, 10-2014-0078664 (2012).
  28. Lee S, Kim BJ, Lee JG, Lim JC, Appl. Chem. Eng., 22(1), 37 (2010)
  29. Chi GY, Appl. Chem. Eng., 27(5), 516 (2016)
  30. Jung KI, Kang YS, Roh SH, Dishwashing concentrated detergent composition, Korean Patent, 10-0203732 (1999).
  31. Park H, Baek SM, Powder detergent composition and preparation method, Korean Patent, 10-2013-001535.
  32. Cho IS, Chi GY, Polypropyleneoxide type cationic surfactant, the method thereof and detergent composition comprising it, Korean Patent, 10-2011-0051444 (2009).