Control of pore in cellulose acetate containing Mg salt by water pressure treatment for applications to separators

Woong Gi Lee; Sang Wook Kang

Journal of Industrial and Engineering Chemistry, Vol.70, 103-106, February, 2019

DOI10.1016/j.jiec.2018.09.035 Export Citation

Control of pore in cellulose acetate containing Mg salt by water pressure treatment for applications to separators

Woong Gi Lee¹, and Sang Wook Kang^{1, 2, †}

¹Department of Chemistry, Sangmyung University, Seoul 03016, Republic of Korea
²Department of Chemistry and Energy Engineering, Sangmyung University, Seoul 03016, Republic of Korea

E-mail:

In this study, we fabricated a porous polymer membrane using Mg(NO3)2 as the additive with water- pressure. The pores in the membrane were fabricated uniformly using Mg(NO3)2ㆍ6H2O and water pressure treatment. Pore size could also be easily controlled by adjusting the water pressure. The generated pores in CA polymers were confirmed by scanning electron microscopy (SEM) images. The coordinate interactions between CA polymer and Mg salts, and ionic states of Mg(NO3)2 were investigated by FT-IR and Raman spectroscopy, respectively. Thus, we succeeded in fabricating porous materials by employing a low-cost, environment-friendly, and simple method with both Mg(NO3)2 and water-pressure.

Keywords:Cellulose acetate;Mg(NO3)2;Water-pressure;Pore;Porosity

[References]

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Weng B, Xu F, Alcoutlabi M, Mao Y, Lozano K, Cellulose, 22(2), 1311 (2015)
Jin SY, Manuel J, Zhao X, Park WH, Ahn JH, J. Ind. Eng. Chem., 45, 15 (2017)
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Dong GY, Hou JW, Wang J, Zhang YT, Chen V, Liu JD, J. Membr. Sci., 520, 860 (2016)
Li X, Liu G, Shi M, Li J, Li J, Guo C, Lee JK, Zheng J, Electrochim. Acta, 3218, 318 (2016)
Jheng LC, Chang WJY, Hsu SLC, Cheng PY, J. Power Sources, 323, 57 (2016)
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Hwang J, Jo C, Hur K, Lim J, Kim S, Lee J, J. Am. Chem. Soc., 136(45), 16066 (2014)
Furukawa H, Gandara F, Zhang YB, Jiang JC, Queen WL, Hudson MR, Yaghi OM, J. Am. Chem. Soc., 136(11), 4369 (2014)
Jiang ZX, Wang YG, Nie HC, Liu YS, Mech. Mater., 104, 139 (2017)
Wang C, Qiao R, Xiao L, Chen L, Ceram. Int., 42, 17179 (2016)
Suib SL, Accounts Chem. Res., 41(4), 479 (2008)
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Anez L, Etienne SC, Primera J, Woignier T, Micro. Meso. Mater., 200, 79 (2014)
Boulter JE, Marschall J, J. Phys. Chem. A, 110(35), 10444 (2006)
Kiso Y, Oguchi T, Kamimoto Y, Makino K, Takeyoshi Y, Yamada T, Sep. Purif. Technol., 173, 286 (2017)
Freemantle M, Chem. Eng. News Arch., 84, 41 (2006)
Kishor R, Ghoshal AK, Energy Fuels, 30(11), 9635 (2016)
Megahed S, Scrosati B, Soc. Interface, 4, 34 (1995)
Bae B, Chun BH, Kim D, Polymer, 42(18), 7879 (2001)
Hou WX, Zhang LZ, Long Y, J. Colloid Interface Sci., 362(2), 629 (2011)
Gong J, Niu R, Liu J, Chen X, Wen X, Mijowska E, Sun Z, Tang T, RSC Adv., 4, 33776 (2014)
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Lee WG, Kim DH, Jeon WC, Kwak SK, Kang SJ, Kang SW, Sci. Rep., 7, 1287 (2017)

[Referenced By]

[1] Du H, Li J, Zhang J, Su G, Li X, Zhao Y, J. Phys. Chem. C, 115(47), 23261 (2011)

[2] Weng B, Xu F, Alcoutlabi M, Mao Y, Lozano K, Cellulose, 22(2), 1311 (2015)

[3] Jin SY, Manuel J, Zhao X, Park WH, Ahn JH, J. Ind. Eng. Chem., 45, 15 (2017)

[4] Sun X, Wu Q, Zhang X, Ren S, Lei T, Li W, Xu G, Zhang Q, Cellulose, 25(2), 1103 (2018)

[5] Dong GY, Hou JW, Wang J, Zhang YT, Chen V, Liu JD, J. Membr. Sci., 520, 860 (2016)

[6] Li X, Liu G, Shi M, Li J, Li J, Guo C, Lee JK, Zheng J, Electrochim. Acta, 3218, 318 (2016)

[7] Jheng LC, Chang WJY, Hsu SLC, Cheng PY, J. Power Sources, 323, 57 (2016)

[8] Wei JS, Ding H, Wang YG, Xing HM, ACS Appl. Mater. Interfaces, 7(10), 5811 (2015)

[9] Hwang J, Jo C, Hur K, Lim J, Kim S, Lee J, J. Am. Chem. Soc., 136(45), 16066 (2014)

[10] Furukawa H, Gandara F, Zhang YB, Jiang JC, Queen WL, Hudson MR, Yaghi OM, J. Am. Chem. Soc., 136(11), 4369 (2014)

[11] Jiang ZX, Wang YG, Nie HC, Liu YS, Mech. Mater., 104, 139 (2017)

[12] Wang C, Qiao R, Xiao L, Chen L, Ceram. Int., 42, 17179 (2016)

[13] Suib SL, Accounts Chem. Res., 41(4), 479 (2008)

[14] Choi S, Watanabe T, Bae TH, Sholl DS, Jones CW, J. Phys. Chem. Lett., 3(9), 1136 (2012)

[15] Zito PF, Caravella A, Brunetti A, Drioli E, Barbieri G, J. Membr. Sci., 523, 456 (2017)

[16] Anez L, Etienne SC, Primera J, Woignier T, Micro. Meso. Mater., 200, 79 (2014)

[17] Boulter JE, Marschall J, J. Phys. Chem. A, 110(35), 10444 (2006)

[18] Kiso Y, Oguchi T, Kamimoto Y, Makino K, Takeyoshi Y, Yamada T, Sep. Purif. Technol., 173, 286 (2017)

[19] Freemantle M, Chem. Eng. News Arch., 84, 41 (2006)

[20] Kishor R, Ghoshal AK, Energy Fuels, 30(11), 9635 (2016)

[21] Megahed S, Scrosati B, Soc. Interface, 4, 34 (1995)

[22] Bae B, Chun BH, Kim D, Polymer, 42(18), 7879 (2001)

[23] Hou WX, Zhang LZ, Long Y, J. Colloid Interface Sci., 362(2), 629 (2011)

[24] Gong J, Niu R, Liu J, Chen X, Wen X, Mijowska E, Sun Z, Tang T, RSC Adv., 4, 33776 (2014)

[25] Shi JL, Fang LF, Li H, Zhang H, Zhu BK, Zhu LP, J. Membr. Sci., 437, 160 (2013)

[26] Yoo SH, Kim CK, Ind. Eng. Chem. Res., 48(22), 9936 (2009)

[27] Lee WG, Kim DH, Jeon WC, Kwak SK, Kang SJ, Kang SW, Sci. Rep., 7, 1287 (2017)