화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.27, No.1, 25-32, January, 2019
DOI10.1007/s13233-019-7030-7  Export Citation
Synthesis of a Novel Fluorescent Cyanide Chemosensor Based on Photoswitching Poly(pyrene-1-ylmethyl-methacrylate-random-methyl methacrylate-random-methacrylate spirooxazine)
Hoan Minh Tran1, Tam Huu Nguyen1, Viet Quoc Nguyen1, Phuc Huynh Tran2, Linh Duy Thai2, Thuy Thu Truong1, Le-Thu T. Nguyen1, and Ha Tran Nguyen1, 3, †
  • 1Faculty of Materials Technology, Ho Chi Minh City University of Technology (HCMUT), Vietnam National University, 268 Ly Thuong Kiet, District 10, Ho Chi Minh City, Vietnam
  • 2Faculty of Chemical Engineering, Ho Chi Minh City University of Technology (HCMUT), Vietnam National University, 268 Ly Thuong Kiet, District 10, Ho Chi Minh City, Vietnam
  • 3Materials Technology Key Laboratory (Mtlab), Vietnam National University, Ho Chi Minh City, 268 Ly Thuong Kiet, District 10, Ho Chi Minh City 70000, Vietnam
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The photoswitching poly(pyrene-1-ylmethyl-methacrylate-random-methyl methacrylate-random-methacrylate spirooxazine) was synthesized via atom transfer radical polymerization and characterized by proton nuclear magnetic resonance (1H NMR), gel permeation chromatography (GPC), Fourier transform infrared (FTIR) spectroscopy, UV-visible spectroscopy, and differential scanning calorimetry (DSC). The obtained copolymer exhibited the capability of erasable and rewritable photoimaging, making it a potential candidate for optical data storage materials. Moreover, the copolymer also showed the sensing ability for cyanide anions effect in aqueous solutions.
Keywords:photoswitching polymers;spirooxazine;atom transfer radical polymerization;chemosensor
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