화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.71, 308-317, March, 2019
DOI10.1016/j.jiec.2018.11.040  Export Citation
A highly efficient MIL-101(Cr)-Graphene-molybdenum oxide nano composite for selective oxidation of hydrogen sulfide into elemental sulfur
Alimohammad Pourreza1, Saeed Askari2, 3, Alimorad Rashidi2, †, Saeed Fakhraie4, Mohammad Kooti1, and Marzieh Shafiei-Alavijeh2
  • 1Department of Chemistry, Shahid Chamran University of Ahvaz, P.O. Box 61357-43169, Ahvaz, Iran
  • 2Nanotechnology Research Center, Research Institute of Petroleum Industry (RIPI), West Blvd. Azadi Sports Complex, P.O. Box 14665, 1998 Tehran, Iran
  • 3Chemical Engineering Department, Sharif University of Technology, Azadi Ave., P.O. Box 11155-9567, Tehran, Iran
  • 4Chemistry Department, Yasouj University, P.O. Box 75918-74831, Yasouj, Iran
E-mail:
Hybrid composites of MIL-101(Cr) and Nanoporous Graphene with ratios in the range of 10-50% were prepared via hydrothermal synthesis method. This study deals with an experimental investigation on selective oxidation of H2S into elemental sulfur in the range of 200-270 °C, the catalyst activity and selectivity toward sulfur was studied. High-temperature reactor tests indicated that the MIL-101(Cr)- NPG50-Mo could be a promising candidate with conversion and selectivity of 100% and 99.5% at 200 °C. The MIL-101(Cr)-NPG50-Mo stability showed there were not any significant changes in physical properties, the activity was evaluated after 20 h which was completely stable without any changes.
Keywords:MIL-101(Cr);Nanocatalyst;Hydrogen sulfide;Selective oxidation;Porous Graphene
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