화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.71, 336-344, March, 2019
DOI10.1016/j.jiec.2018.11.044  Export Citation
Acid-mediated surface etching of a nano-sized metal-organic framework for improved reactivity in the fixation of CO2 into polymers
Sudakar Padmanaban, Minog Kim, and Sungho Yoon†
  • Department of Applied Chemistry, Kookmin University, 861-1 Jeongneung-dong, Seongbuk-gu, Seoul 136702, Republic of Korea
E-mail:
Engineering the surface of Metal-organic frameworks (MOFs) will afford to advantageously improve their performances in catalysis. A particular example of industrially applied MOF-based catalysis is the zinc glutarate (ZnGA) catalyzed copolymerization of CO2 with an epoxide. Herein, we demonstrate how the modification of the surface of ZnGA aids to enhance its productivity in fixing CO2 into poly(alkylene carbonates), and deliver an industrially viable procedure to prepare a nanosized, surface-etched ZnGA by systematically controlling the reaction conditions and by using a mild-HCl solution. This surface modified-ZnGA exhibits 83% increased productivity than the standard-ZnGA and thus could be readily applicable in industries.
Keywords:Metal-organic frameworks;Heterogeneous catalyst;Zinc glutarate;Surface etching;CO2;Poly(alkylene carbonate)
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