화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.72, 100-106, April, 2019
DOI10.1016/j.jiec.2018.12.007  Export Citation
A tailored molecular imprinting ratiometric fluorescent sensor based on red/blue carbon dots for ultrasensitive tetracycline detection
Xiqing Liu, Tao Wang1, Wenjuan Wang1, Zhiping Zhou†, and Yongsheng Yan1
  • School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China
  • 1Institute of Green Chemistry and Chemical Technology, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China
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The molecular imprinting ratiometric fluorescence sensor has exhibited great potential in biological and environmental detection because of the combination between the excellent selectivity of molecular imprinting technique and outstanding robustness of ratiometric measurement methods On this basis, two kinds of different well-resolved wavelengths and high-fluorescent carbon dots (CDs) were prepared by various solvent extraction using osmanthus fragrans leaves as carbon source. Then the ratiometric fluorescence sensor (MIPs@rCDs/bCDs@SiO2) has been constructed by the obtained CDs which the redemission CDs (rCDs) were used to responsive signal and the blue-emission CDs (bCDs) was served as reference signal and applied for highly selective and excellent sensitive detection of tetracycline (TC). Under optimum conditions, the ratiometric fluorescence MIPs@rCDs/bCDs@SiO2 sensor has also exhibited lower detection limit of 1.19 nM and the linear range of 0.50 nM. The ratiometric fluorescence sensor was further successfully employed to the determination of TC in water samples gathered from local river water and tap water, indicating its great worth toward water sample analysis in complicated environments.
Keywords:Carbon dots;Ratiometric fluorescence sensor;Molecular imprinting polymer;Ultrasensitive detection;Tetracycline
  1. Kasprzyk W, Swiergosz T, Bednarz S, Walas K, Bashmakova NV, Bogdał D, Nanoscale, 10, 13889 (2018)
  2. Zhang M, Hu L, Wang H, Song Y, Liu Y, Li H, Shao M, Huang H, Kang Z, Nanoscale, 10, 12734 (2018)
  3. Jin M, Liu X, Zhang X, Wang L, Bing T, Zhang N, Zhang Y, Shangguan D, ACS Appl. Mater. Interfaces, 10, 25166 (2018)
  4. Baptista FR, Belhout SA, Giordani S, Quinn SJ, Chem. Soc. Rev., 44, 4433 (2015)
  5. Qu FL, Pei HM, Kong RM, Zhu SY, Xia L, Talanta, 165, 136 (2017)
  6. Chao D, Lyu W, Liu Y, Zhou L, Zhang Q, Deng R, Zhang H, J. Mater. Chem. C, 6, 7527 (2018)
  7. Jaleel JA, Pramod K, J. Control. Release, 269, 302 (2018)
  8. Sharma V, Kaur N, Tiwari P, Saini AK, Mobin SM, Carbon, 139, 393 (2018)
  9. Peng Z, Han X, Li S, Al-Youbi AO, Bashammakh AS, El-Shahawi MS, Leblanc RM, Coord. Chem. Rev., 343, 256 (2017)
  10. Zhu MM, Han MM, Zhu C, Hu LL, Huang H, Liu Y, Kang ZH, J. Colloid Interface Sci., 530, 256 (2018)
  11. Kang R, Park S, Yun KJ, Dong CL, Cha MJ, Seo JH, Cho S, Adv. Eng. Mater., 8, 170216 (2018)
  12. Zhou S, Tang R, Yin L, Adv. Mater., 29, 170368 (2017)
  13. Ostadhossein F, Benig L, Tripathi I, Misra SK, Pan D, ACS Appl. Mater. Interfaces, 10, 19408 (2018)
  14. Yuan B, Guan S, Sun X, Li X, Zeng H, Xie Z, Chen P, Zhou S, ACS Appl. Mater. Interfaces, 10, 16005 (2018)
  15. Liu H, Ye T, Mao C, Angew. Chem.-Int. Edit., 46, 6473 (2007)
  16. Zhang X, Jiang M, Niu N, Chen Z, Li S, Liu S, Li J, ChemSusChem, 11, 11 (2018)
  17. Wu S, Li W, Zhou W, Zhan Y, Hu C, Zhuang J, Zhang H, Zhang X, Lei B, Liu Y, Adv. Opt. Mater., 6, 170115 (2018)
  18. Zou WS, Ye CH, Wang YQ, Li WH, Huang XH, Sens. Actuators B-Chem., 271, 54 (2018)
  19. Chen W, Yue X, Sheng J, Li W, Zhang L, Su W, Huang C, Song X, Sens. Actuators B-Chem., 258, 125 (2017)
  20. Chao J, Wang X, Liu Y, Zhang Y, Huo F, Yin C, Zhao M, Sun J, Xu M, Sens. Actuators B-Chem., 272, 195 (2018)
  21. Du J, Gu Q, Chen J, Fan J, Peng X, Sens. Actuators B-Chem., 265, 204 (2018)
  22. Jun Y, Wang T, Hwang S, Kim D, Ma D, Kim K, Kim S, Jung J, Ahn K, Angew. Chem.-Int. Edit., 57, 1 (2018)
  23. Wackerlig J, Lieberzeit PA, Sens. Actuators B-Chem., 207, 144 (2015)
  24. Uzun L, Turner APF, Biosens. Bioelectron., 76, 131 (2016)
  25. Xu S, Lu H, Chem. Commun., 51, 3200 (2015)
  26. Wang X, Yu S, Liu W, Fu L, Wang Y, Li J, Chen L, ACS Sens., 3, 378 (2018)
  27. Wei JR, Chen HY, Zhang W, Pan JX, Dang FQ, Zhang ZQ, Zhang J, Sens. Actuators B-Chem., 244, 31 (2017)
  28. Zhang XP, Zhang RR, Yang AJ, Wang Q, Kong RM, Qu FL, Microchim. Acta., 184, 4367 (2017)
  29. Jiang X, Guo YH, Zhang LB, Jiang WJ, Xie RZ, Chem. Eng. J., 341, 392 (2018)
  30. Wang J, Cheng R, Wang Y, Sun L, Chen L, Dai X, Pan J, Pan G, Yan Y, Sens. Actuators B-Chem., 263, 533 (2018)
  31. Guan RP, Yuan XZ, Wu ZB, Wang H, Jiang LB, Zhang J, Li YF, Zeng GM, Mo D, Chem. Eng. J., 350, 573 (2018)
  32. Yan P, Jiang D, Tian Y, Xu L, Qian J, Li H, Xia J, Li H, Biosens. Bioelectron., 111, 74 (2018)
  33. Jang HM, Yoo S, Choi YK, Park S, Kan E, Bioresour. Technol., 259, 24 (2018)
  34. Fernandez R, Ruiz AI, Garcia-Delgado C, Gonzalez-Santamaria DE, Anton-Herrero R, Yunta F, Poyo C, Hernandez A, Eymar E, Cuevas J, Sci. Total Environ., 645, 146 (2018)
  35. Stober W, Fink A, Bohn E, J. Colloid Interface Sci., 26, 62 (1968)
  36. Yong Y, Pang H, Yang HB, Guo C, Shao J, Chi Y, Li CM, Yu T, Angew. Chem.-Int. Edit., 52, 7800 (2013)
  37. Shen Z, Zhang C, Yu X, Li J, Wang Z, Zhang Z, Liu B, J. Mater. Chem. C, 6, 9636 (2018)
  38. Bhati A, Anand SR, Kumar G, Garg A, Khare P, Sonkar SK, ACS Sustain. Chem. Eng., 6, 9246 (2018)
  39. Pei HM, Zhu SY, Yang MH, Kong RM, Zheng YQ, Qu FL, Biosens. Bioelectron., 74, 909 (2015)
  40. Song W, Duan W, Liu Y, Ye Z, Chen Y, Chen H, Qi S, Wu J, Liu D, Xiao L, Ren C, Chen X, Anal. Chem., 89, 13626 (2017)
  41. Kumar A, Khan M, Zeng XK, Lo IMC, Chem. Eng. J., 353, 645 (2018)
  42. Li X, Wang W, Li Q, Lin H, Xu Y, Zhuang L, Mater. Des., 151, 89 (2018)
  43. Shi W, Guo F, Han M, Yuan S, Guan W, Li H, Huang H, Liu Y, Kang Z, J. Mater. Chem. B, 5, 3293 (2017)
  44. Li H, Zhao L, Xu Y, Zhou T, Liu H, Huang N, Ding J, Li Y, Ding L, Talanta, 185, 542 (2018)
  45. Xu J, Shen XK, Jia L, Zhou T, Ma TL, Xu ZQ, Cao JL, Ge ZJ, Bi N, Zhu TF, Guo SL, Li XH, J. Hazard. Mater., 342, 158 (2018)
  46. Liu Y, Yan K, Zhang J, ACS Appl. Mater. Interfaces, 8, 28255 (2016)
  47. Li W, Zhu J, Xie G, Ren Y, Zheng YQ, Anal. Chim. Acta, 1022, 131 (2018)