화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.72, 157-169, April, 2019
DOI10.1016/j.jiec.2018.12.015  Export Citation
Preparation of ortho-symmetric double (OSD) Z-scheme SnO2/CdSe/Bi2O3 sonocatalyst by ultrasonic-assisted isoelectric point method for effective degradation of organic pollutants
Siyi Li, Meng Zhang, Xue Ma1, Jing Qiao, Hongbo Zhang, Jun Wang†, and Youtao Song1, †
  • College of Chemistry, Liaoning University, Shenyang 110036, PR China
  • 1College of Environment, Liaoning University, Shenyang 110036, PR China
E-mail:,
In this work, an ortho-symmetric double (OSD) Z-scheme SnO2＼CdSe/Bi2O3 sonocatalyst is skillfully designed and synthesized via ultrasonic-assisted isoelectric point method and then the sonocatalytic activity is studied under ultrasonic irradiation in the degradation of organic contaminants. The effects of ultrasonic irradiation time, sonocatalyst dosage, initial Rhodamine B concentration, organic dye kind and used times are investigated systemically. The formation of OH and h+ are confirmed by using t-BuOH and oxalate, respectively. The Rhodamine B can completely be degraded under given experimental conditions such as 10 mg/L Rhodamine B solution, 1.00 g/L OSD Z-scheme SnO2＼CdSe/Bi2O3 dosage and 150 min ultrasonic process. The formation of mainly intermediate products is studied by Liquid Chromatography. Mass Spectrometry. Moreover, the sonocatalytic reaction mechanism caused by OSD Z-scheme SnO2＼CdSe/Bi2O3 is presented.
Keywords:Ortho-symmetric double (OSD) Z-scheme;sonocatalytic system;SnO2＼CdSe/Bi2O3 composite;Ultrasonic-assisted isoelectric point method;Sonocatalytic degradation;Organic contaminants
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