Journal of Industrial and Engineering Chemistry, Vol.72, 504-511, April, 2019
Facile Synthesis of quantum dots SnO2/Fe3O4 hybrid composites for superior reversible lithium-ion storage
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Quantum dots SnO2/Fe3O4 hybrid composites were synthesized by galvanic replacement reaction between Fe3+ ions and Sn and were utilized as anodes for lithium-ion batteries. The composites at few-nanometer scale showed different compositions of SnO2 and Fe3O4 with different reaction time. The composites exhibited significantly enhanced electrochemical performance; for instance, SnO2/Fe3O4-18 h electrode delivered a reversible capacity of 1300 mAh g-1 after 100 cycles and a rate capacity of 507 mAh g-1 at 10 A g-1. The notable performance was ascribed to the presence of quantum dotsnanostructures and inactive phases and to the generation of a short Li+-ion diffusion pathway.
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