화학공학소재연구정보센터
Journal of the American Chemical Society, Vol.116, No.8, 3507-3512, 1994
Dynamics of Structural Rearrangements in the Water Trimer
The internal dynamics of the hydrogen bonding network of the water trimer are investigated by tunable far-infrared laser spectroscopy. New intermolecular vibrations have been measured at 87.1 [(H2O)(3)] and 98.1 cm(-1) [(D2O)(3)]. Symmetry restrictions produce an exact oblate symmetric rotor pattern in the spectrum, even though theory predicts the trimer structure to be an asymmetric near-planar ring. In addition, each rovibrational transition is split into a quartet. A group theoretical treatment identifies two classes of structural rearrangements to account for these effects.