Novel polyvinylidene fluoride (PVDF) ultrafiltration (UF) membranes were facilely fabricated using polyvinyl alcohol (PVA) aqueous solution as the coagulation bath through phase inversion method. In the process, PVA was introduced into the pore surfaces of the PVDF membranes via the interdiffusion of the non-solvent water and the solvent. The effects of PVA content in the coagulation bath on membrane properties were systematically discussed. The results indicated that the increase of PVA content in coagulation bath resulted in the formations of the more sponge-like structures and the higher surface hydrophilicity. Smaller pore size led to lower water flux and higher bovine serum albumin rejection. Fouling resistance measurement indicated that the membranes made in PVA/water coagulation bath had higher flux recovery ratio (92.1%) than the membrane made in a pure water bath (71.0%). Furthermore, mechanical property test revealed that the resulting membranes had high tensile strength and Young's modulus. In this work, we found that the morphology and the property of the novel PVDF membranes could be determined by the PVA content in the coagulation bath. POLYM. ENG. SCI., 59:E384-E393, 2019. (c) 2018 Society of Plastics Engineers