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Polymer Engineering and Science, Vol.59, No.1, 206-215, 2019
Toughening of epoxy systems by brominated epoxy
Blends of brominated epoxy (BE) and conventional epoxy resins were studied following curing with aliphatic triethylenetetramine (TETA), etheric (polyether diamine- PEA4), and aromatic (3,3 '-diamino diphenyl sulfone [DDS]) hardeners. The addition of BE resulted in an increase in T-g in all tested blends. Blends with 50 wt% BE cured with TETA demonstrated an increase in flexural modulus and flexural strength, while preserving the elongation. Blends with 40 wt% BE cured with PEA4 and 50 wt% BE cured with DDS resulted in a significant enhanced tensile elongation. The shear strength of all cured systems decreased moderately with the addition of BE exhibiting a mixed mode failure. Analysis of the fracture morphology using electron microscopy supported the increase of toughness levels as a result of incorporating BE to conventional epoxy. A unique nodular and rough fracture morphology was obtained, which is related to a toughening mechanism caused by the addition of BE. It was concluded that blends of BE and conventional epoxy could be used as structural adhesives having high T-g, enhanced mechanical properties and increased toughness. POLYM. ENG. SCI., 59:206-215, 2019. (c) 2018 Society of Plastics Engineers