화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Applied Chemistry for Engineering, Vol.30, No.2, 133-140, April, 2019
DOI10.14478/ace.2019.1016  Export Citation
2차원 이황화몰리브덴의 성질, 제조 및 에너지 저장 소자 응용
Properties, Preparation, and Energy Storage Applications of Two-dimensional Molybdenum Disulfide
최봉길†
  • 강원대학교 화학공학과
Bong Gill Choi†
  • Department of Chemical Engineering, Kangwon National University, 346 Joongang-ro, Samcheok, Gangwon-do 25913, Republic of Korea
E-mail:
Two-dimensional (2D) ultrathin molybdenum dichalcogenides MoS2 has gained a great deal of attention in energy conversion and storage applications because of its unique morphology and property. The 2D MoS2 nanosheets provide a high specific surface area, 2D charge channel, sub-nanometer thickness, and high conductivity, which lead to high electrochemical performances for energy storage devices. In this paper, an overview of properties and synthetic methods of MoS2 nanosheets for applications of supercapacitors and rechargeable batteries is introduced. Different phases triangle prismatic 2H and metallic octahedral 1T structured MoS2 were characterized using various analytical techniques. Preparation methods were focused on top-down and bottom-up approaches, including mechanical exfoliation, chemical intercalation and exfoliation, liquid phase exfoliation by the direct sonication, electrochemical intercalation exfoliation, microwave-assisted exfoliation, mechanical ball-milling, and hydrothermal synthesis. In addition, recent applications of supercapacitors and rechargeable batteries using MoS2 electrode materials are discussed.
Keywords:MoS2;Supercapacitor;Batteries;Composite;Electrochemistry
  1. Lukatskaya MR, Dunn B, Gogotsi Y, Nat. Commun., 7, 12647 (2016)
  2. Salanne M, Rotenber B, Naoi K, Kaneko K, Taberna PL, Grey CP, Dunn B, Simon P, Nat. Energy, 1, 16070 (2016)
  3. Simon P, Gogotsi Y, Dunn B, Science, 343(6176), 1210 (2014)
  4. Chen GZ, Int. Mater. Rev., 62, 173 (2017)
  5. Xiao X, Wang H, Urbankowski P, Gogotsi Y, Chem. Soc. Rev., 47, 8744 (2018)
  6. Ke X, Prahl JM, Alexander JID, Wainright JS, Zawodzinski TA, Savinell RF, Chem. Soc. Rev., 47, 8721 (2018)
  7. Wang Q, Jiang L, Sun J, Nano Energy, 55, 93 (2019)
  8. Zhang P, Wang F, Yu M, Zhuang X, Feng X, Chem. Soc. Rev., 47, 7426 (2018)
  9. Zou F, Chen YM, Liu K, Yu Z, Liang W, Bhaway SM, Gao M, Zhu Y, ACS Nano, 10, 377 (2016)
  10. Zou Y, Rui X, Sun W, Xu Z, Zhou Y, Ng WJ, Yan Q, Fong E, ACS Nano, 9, 4628 (2015)
  11. Crowe AJ, Stringham KK, Dimeglio JL, Bartlett BM, J. Phys. Chem. C, 121, 7711 (2017)
  12. Tan YH, Yao WT, Zhang T, Ma T, Lu LL, Zhou F, Yao HB, Yu SH, ACS Nano, 12, 5856 (2018)
  13. Sun J, Wu C, Sun X, Hu H, Zhi C, Houa L, Yuan C, J. Mater. Chem. A, 5, 9443 (2017)
  14. Choudhary N, Li C, Moore J, Nagaiah N, Zhai L, Jung Y, Thomas J, Adv. Mater., 29, 160533 (2017)
  15. Wu HR, Lian K, J. Power Sources, 378, 209 (2018)
  16. Nueangnoraj K, Ruiz-Rosas R, Nishihara H, Shiraishi S, Morallon E, Cazorla-Amoros D, Kyotani T, Carbon, 67, 792 (2018)
  17. Wang JG, Yang Y, Huang ZH, Kang F, Carbon, 61, 190 (2013)
  18. Yang M, Lee KG, Lee SJ, Lee SB, Han YK, Choi BG, ACS Appl. Mater. Interfaces, 7, 22364 (2015)
  19. Wang F, Xiao S, Hou Y, Hu C, Liu L, Wu Y, RSC Adv., 3, 13059 (2013)
  20. Wang Q, Yan J, Fan Z, Energy Environ. Sci., 9, 729 (2016)
  21. Mendoza-Sanchez B, Gogotsi Y, Adv. Mater., 28(29), 6104 (2016)
  22. Chen Y, Pang WK, Bai H, Zhou T, Liu Y, Li S, Guo Z, Nano Lett., 17, 429 (2016)
  23. Couly C, Alhabeb M, Van Aken KL, Kurra N, Gomes L, Navarro-Suarez AM, Anasori B, Alshareef HN, Gogotsi Y, Adv. Electron. Mater., 4, 170033 (2018)
  24. Lei Z, Zhang J, Zhao XS, J. Mater. Chem., 22, 153 (2012)
  25. Ghasemi F, Jalali M, Abdollahi A, Mohammadi S, Sanaee Z, Mohajerzadeh S, RSC Adv., 7, 52772 (2017)
  26. Kumar KS, Choudhary N, Jung Y, Thomas J, ACS Energy Lett., 3, 482 (2018)
  27. Zhang WJ, Huang KJ, Inorg. Chem. Front., 4, 1602 (2017)
  28. Wang T, Chen S, Pang H, Xue H, Yu Y, Adv. Sci., 4, 160028 (2017)
  29. Iro ZS, Subramani C, Dash SS, Int. J. Electrochem. Sci., 11, 10628 (2016)
  30. Zhang G, Liu H, Qu J, Li J, Energy Environ. Sci., 9, 1190 (2016)
  31. Chhowalla M, Shin HS, Eda G, Li LJ, Loh KP, Zhang H, Nat. Chem., 5, 263 (2013)
  32. Hinnemann B, Moses PG, Bonde J, Jorgensen KP, Nielsen JH, Horch S, Chorkendorff L, Norskov JK, J. Am. Chem. Soc., 127(15), 5308 (2005)
  33. Tongay S, Zhou J, Ataca C, Lo K, Mattenws TS, Li J, Grossman JC, Wu J, Nano Lett., 12, 5576 (2012)
  34. Shi S, Sun Z, Hu YH, J. Mater. Chem. A, 6, 23932 (2018)
  35. Jeong JM, Kang HG, Kim HJ, Hong SB, Jeon H, Hwang SY, Seo D, Kwak BE, Han YK, Choi BG, Kim DH, Adv. Funct. Mater., 28, 180295 (2018)
  36. Novoselov KS, Jiang D, Schedin F, Booth TJ, Khotkevich VV, Morozov SV, Geim AK, Proc. Natl. Acad. Sci. U.S.A., 102, 10451 (2005)
  37. Zeng Z, Yin Z, Huang X, Li H, He Q, Lu G, Boey F, Zhang H, Angew. Chem.-Int. Edit., 50, 11093 (2011)
  38. Joensen P, Frindt RF, Morrison SR, Mater. Res. Bull., 21, 457 (1986)
  39. Zeng Z, Sun T, Zhu J, Huang X, Yin Z, Lu G, Fan Z, Yan Q, Hng HH, Zhang H, Angew. Chem.-Int. Edit., 51, 9052 (2012)
  40. Cheng P, Sun K, Hu YH, RSC Adv., 6, 65691 (2016)
  41. Reshmi S, Akshaya MV, Satpati B, Basu PK, Bhattacharjee K, Nanotechnology, 29, 205604 (2018)
  42. Qi Y, Xu Q, Wang Y, Yan B, Ren Y, Chen Z, ACS Nano, 10, 2903 (2016)
  43. Chi ZH, Zhao XM, Zhang H, Goncharov AF, Lobanov SS, Kagayama T, Sakata M, Chen XJ, Phys. Rev. Lett., 113, 036802 (2014)
  44. Geng X, Sun W, Wu W, Chen B, Al-Hilo A, Benamara M, Zhu H, Watanabe F, Cui J, Chen T, Nat. Commun., 7, 10672 (2016)
  45. Liu Q, Li XL, He Q, Khalil A, Liu DB, Xiang T, Wu XJ, Song L, Small, 11, 5556 (2015)
  46. Liu ZP, Gao ZC, Liu YH, Xia MS, Wang RW, Li N, ACS Appl. Mater. Interfaces, 9, 25291 (2017)
  47. Choudhary N, Patel M, Ho YH, Dahotre NB, Lee W, Hwang JY, Choi W, J. Mater. Chem. A, 3, 24049 (2015)
  48. Karade SS, Dubal DP, Sankapal BR, RSC Adv., 6, 39159 (2016)
  49. Acerce M, Voiry D, Chhowalla M, Nat. Nanotechnol., 10(4), 313 (2015)
  50. Xuyen NT, Ting JM, Chem. Eng. J., 23, 17348 (2017)
  51. Huang KJ, Wang L, Zhang JZ, Xing K, J. Electroanal. Chem., 752, 33 (2015)
  52. Khawula TNY, Raju K, Franklyn PJ, Sigalas L, Ozoemena KI, J. Mater. Chem. A, 4, 6411 (2016)
  53. Zhang Y, He T, Liu G, Zu L, Yang J, Nanoscale, 9, 10059 (2017)
  54. Wang J, Wu Z, Yin H, Li W, Jiang Y, RSC Adv., 4, 56926 (2014)
  55. Yang C, Chen Z, Shakir I, Xu Y, Lu H, Nano Res., 9, 951 (2016)
  56. Pan Q, Zheng F, Ou X, Yang C, Xiong X, Tang Z, Zhao L, Liu M, ACS Sustain. Chem. Eng., 5, 4739 (2017)
  57. Wang MQ, Fei HF, Zhang P, Yin LW, Electrochim. Acta, 209, 389 (2016)
  58. Jeon H, Jeong JM, Kang HG, Kim HJ, Park J, Kim DH, Jung YM, Hwang SY, Han YK, Choi BG, Adv. Eng. Mater., 8, 180022 (2018)
  59. Xie D, Wang DH, Tang WJ, Xia XH, Zhang YJ, Wang XL, Gu CD, Tu JP, J. Power Sources, 307, 510 (2016)
  60. Zhang S, Chowdari BVR, Wen Z, Jin J, Yang J, ACS Nano, 9, 12464 (2015)
  61. Xu J, Tang H, Chu Y, Li C, RSC Adv., 5, 48492 (2015)
  62. Veeramalai CP, Li F, Xu H, Kimb TW, Guo T, RSC Adv., 5, 57666 (2015)
  63. Wang HY, Wang BY, Wang D, Lu L, Wang JG, Jiang QC, RSC Adv., 5, 58084 (2015)
  64. Zhou Y, Liu Y, Zhao WX, Xu RM, Wang DH, Li BJ, Zhou X, Shen H, Electrochim. Acta, 211, 1048 (2016)
  65. Wu M, Zhan J, Wu K, Li Z, Wang L, Geng B, Wang L, Pan D, J. Mater. Chem. A, 5, 14061 (2017)
  66. Wang T, Sun C, Yang M, Zhao G, Wang S, Ma F, Zhang L, Shao Y, Wu Y, Huang B, Hao X, J. Alloy. Compd., 716, 112 (2017)
  67. Chen B, Zhao N, Guo L, He F, Shi C, He C, Li J, Liu E, Nanoscale, 7, 12895 (2015)
  68. Wang M, Fan L, Tian D, Wu X, Qiu Y, Zhao C, Guan B, Wang Y, Zhang N, Sun K, ACS Energy Lett., 3, 1627 (2018)
  69. Jeong YC, Kim JH, Kwon SH, Oh JY, Park J, Jung Y, Lee SG, Yang SJ, Park CR, J. Mater. Chem. A, 5, 23909 (2017)
  70. Dan S, Delai Y, Ping L, Yougen T, Jun G, Lianzhou W, Haiyan W, Adv. Eng. Mater., 8, 170238 (2018)
  71. Li Y, Liang Y, Hernandez FCR, Yoo HD, An Q, Yao Y, Nano Energy, 15, 453 (2015)
  72. Liang YL, Yoo HD, Li YF, Shuai J, Calderon HA, Hernandez FCR, Grabow LC, Yao Y, Nano Lett., 15, 2194 (2015)
  73. Liu YC, Fan LZ, Jiao LF, J. Power Sources, 340, 104 (2017)