화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.73, 221-232, May, 2019
DOI10.1016/j.jiec.2019.01.028  Export Citation
Enhanced catalytic performance of Cr-inserted hydrotalcites in the liquid oxidation of styrene
Nguyen Tien Thao†, and Le Thi Kim Huyen
  • Faculty of Chemistry, Vietnam National University Hanoi, 19 - Le Thanh Tong Stress, Hanoi 100000, Vietnam
E-mail:
Chromium(III) ions were inserted in magnesium hydroxide layers via co-precipitation route. In the low-chromium content sample, Cr(III) ions are present mostly at octahedral sites of metal hydroxide layers, while some Cr(VI) species formed on the external surface of the high-chromium content catalyst. The Cr-doped metal hydroxide layer ions play as active sites for the oxidation of styrene with H2O2 at a low temperature. The insertion of chromium(III) in the brucite-like sheets enhanced catalytic stability of catalysts in the oxidation of styrene. The Cr-doped hydrotalcites showed a good activity (50-60%), and high selectivity to benzaldehyde (80-85%) at room temperature.
Keywords:Selective oxidation;Cr-doped hydrotalcite;Styrene;Stability;Chromium
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