화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.74, 1-6, June, 2019
DOI10.1016/j.jiec.2019.03.006  Export Citation
Ionene copolymer electrolyte obtained from cyclo-addition of di-alkyne and di-azide monomers for solid-state smart glass windows
John Marc C. Puguan, and Hern Kim†
  • Department of Energy Science and Technology, Smart Living Innovation Technology Center, Myongji University, Yongin, Gyeonggi-do 17058, Republic of Korea
E-mail:
A copoly(ionic liquid) (coPIL) based on 1,2,3-triazolium bearing trioxyethylene and tetraoxyethylene spacers was successfully synthesized as electrolyte for all-solid state electrochromic devices (ECD). This polyelectrolyte was produced by reacting triethylene glycol (TEG3)-diazide and tetraethylene glycol (TEG4)-dialkyne monomers through a ‘click’ reaction, copper-catalyzed alkyne-azidecycloadditon (CuAAC), and subsequently underwent several alkylation and anion metathesis. The new coPIL bearing ethylene glycol fragments exhibited excellent thermal degradation temperature (Td10 = 230 °C) and ionic conductivity (σ = 8.8 x 10 -5 S cm-1) which resulted to an efficient color switching (tc = 11.8 s and tb = 6.2 s), a high optical contrast (ΔT = 24%) and a remarkable stability (after 3000 cycles) of a symmetric all-solid-state smart glass window. The structural design of this new polyelectrolyte material and its corresponding properties make it an excellent electrolyte for many electrochemical devices that require zero electrolyte leakage.
Keywords:Electrochromic devices;Smart windows;Copoly(ionic liquid);Polyelectrolyte;1,2,3-triazole;Click chemistry
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