Effect of surface modification of CaCO3 nanoparticles by a silane coupling agent methyltrimethoxysilane on the stability of foam and emulsion

JuYeon Lee; Seon Hui Jo; JongChoo Lim

Journal of Industrial and Engineering Chemistry, Vol.74, 63-70, June, 2019

DOI10.1016/j.jiec.2019.02.002 Export Citation

Effect of surface modification of CaCO3 nanoparticles by a silane coupling agent methyltrimethoxysilane on the stability of foam and emulsion

JuYeon Lee, Seon Hui Jo, and JongChoo Lim^†

Department of Chemical and Biochemical Engineering, Dongguk University-Seoul, 3-26 Phil-Dong, Choong-Ku, Seoul 100-715, Republic of Korea

E-mail:

In this study, the surface modification of CaCO3 nanoparticles was performed by using a silane coupling agent methyltrimethoxysilane (MTMS) and effect of surface hydrophobicity on the stability of foam and emulsion was investigated. In order to confirm surface modification of CaCO3 nanoparticles by MTMS, Fourier infrared spectroscopy, differential scanning calorimetry, and thermogravimetric analysis have been carried out. Atomic concentration of CaCO3 particle surface treated by MTMS has been identified by using X-ray diffractometer and X-ray photoelectron spectroscopy analysis. The active ratio for the CaCO3 nanoparticles modified by MTMS was found to be 96.6 ± 0.4% at 15 wt% of MTMS concentration where the contact angle of water on the CaCO3 surface modified by MTMS was found to be 89.6 ± 0.4 °. Both stable emulsion and foam were formed at 15 wt% of MTMS concentration, suggesting that CaCO3 nanoparticle treated by a silane coupling agent MTMS is a strong candidate for the potential applicability as a stabilizer for foam and emulsion.

Keywords:CaCO3 nanoparticle;Surface modification;Methyltrimethoxysilane (MTMS);Emulsion stability;Foam stability

[References]

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Premphet K, Horanont P, Polymer, 41(26), 9283 (2000)
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Keler DS, Luner P, Colloids Surf. A: Physicochem. Eng. Asp., 161, 401 (2000)
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Mihajlovic S, Dakovic A, Sekulic Z, Jovanovic V, Vucinic D, J. Serb. Chem. Soc., 67, 1 (2009)
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Tiberg F, Brinck J, Grant L, Curr. Opin. Colloid Interface Sci., 4, 411 (1999)
Somasundaran P, Huang L, Adv. Colloid Interface Sci., 88, 179 (2000)
Song EM, Kim DW, Lim JC, J. Ind. Eng. Chem., 28, 351 (2015)
Kim DW, Lee JY, Lee SM, Lim JC, Colloids Surf. A: Physicochem. Eng. Asp., 536, 213 (2018)
Shimpi N, Mali A, Hansora DP, Mishra S, Nanosci. Nanoeng., 3, 8 (2015)
Mishra S, Chatterjee A, Singh R, Polym. Adv. Technol., 22, 2571 (2011)
Mavropoulos E, Costa AM, Costa LT, Achete CA, Mello A, Granjeiro JM, Rossi AM, Colloids Surf. B: Biointerfaces, 83, 1 (2011)
Ghosh S, Goswami SK, Mathias LJ, J. Mater. Chem. A, 1, 6073 (2013)
Ek S, Root A, Peussa M, Niinisto L, Thermochim. Acta, 379(1-2), 201 (2001)
Binks BP, Lumsdon SO, Langmuir, 16(23), 8622 (2000)
Binks BP, Rodrigues JA, Angew. Chem.-Int. Edit., 46, 5389 (2007)
Binks BP, Rodrigues JA, Colloids Surf. A: Physicochem. Eng. Asp., 345, 195 (2009)
Binks BP, Lumsdon SO, Langmuir, 16(8), 3748 (2000)
Zhang J, Li L, Xu J, Sun D, Colloid Polym. Sci., 292, 441 (2014)
Cho WG, J. Soc. Cosmet. Sci. Korea, 36, 1 (2010)
Tambe DE, Sharma MM, J. Colloid Interface Sci., 157, 244 (1993)
Binks BP, Horozov TS, Angew. Chem.-Int. Edit., 117, 3788 (2005)
Rio E, Drenckhan W, Salonen A, Langevin D, Adv. Colloid Interface Sci., 205, 74 (2014)
Fletcher PDI, Holt B, Langmuir, 27(21), 12869 (2011)
Gonzenbach UT, Studart AR, Tervoort E, Gauckler LJ, Angew. Chem.-Int. Edit., 45, 3526 (2006)

[Referenced By]

[1] Binks BP, Curr. Opin. Colloid Interface Sci., 7, 21 (2002)

[2] Cui ZG, Cui YZ, Cui CF, Chen Z, Binks BP, Langmuir, 26(15), 12567 (2010)

[3] Wang C, Sheng Y, Bala H, Zhao X, Zhao J, Ma X, Wang Z, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 27, 42 (2007)

[4] Premphet K, Horanont P, Polymer, 41(26), 9283 (2000)

[5] Wang CY, Piao C, Zhai XL, Hickman FN, Li J, Powder Technol., 198(1), 131 (2010)

[6] Keler DS, Luner P, Colloids Surf. A: Physicochem. Eng. Asp., 161, 401 (2000)

[7] Osman MA, Suter UW, Chem. Mater., 14, 4408 (2002)

[8] Mihajlovic S, Dakovic A, Sekulic Z, Jovanovic V, Vucinic D, J. Serb. Chem. Soc., 67, 1 (2009)

[9] Song EM, Kim DW, Kim BJ, Lim JC, Colloids Surf. A: Physicochem. Eng. Asp., 461, 1 (2014)

[10] Demjen Z, Pukanszky B, Nagy J, Polymer, 40(7), 1763 (1999)

[11] Fekete E, Pukanszky B, J. Colloid Interface Sci., 194(2), 269 (1997)

[12] Yang ZY, Tang YJ, Zhang JH, Chalcogenide Lett., 10, 131 (2013)

[13] Deshmukh GS, Pathak SU, Peshwe DR, Ekhe JD, Bull Mater. Sci., 33, 277 (2010)

[14] Yin Y, Wang X, Adv. Mat. Res., 79-82, 1967 (2009)

[15] Liao J, Du G, Qiao X, Hao D, J. Chin. Ceram. Soc., 39, 641 (2011)

[16] Esumi K, Ueno M, Structure-Performance Relationships in Surfactant, Marcel Dekker, New York, 1997.

[17] Grosse I, Estel K, Colloid Polym. Sci., 278, 1000 (2000)

[18] Tiberg F, Brinck J, Grant L, Curr. Opin. Colloid Interface Sci., 4, 411 (1999)

[19] Somasundaran P, Huang L, Adv. Colloid Interface Sci., 88, 179 (2000)

[20] Song EM, Kim DW, Lim JC, J. Ind. Eng. Chem., 28, 351 (2015)

[21] Kim DW, Lee JY, Lee SM, Lim JC, Colloids Surf. A: Physicochem. Eng. Asp., 536, 213 (2018)

[22] Shimpi N, Mali A, Hansora DP, Mishra S, Nanosci. Nanoeng., 3, 8 (2015)

[23] Mishra S, Chatterjee A, Singh R, Polym. Adv. Technol., 22, 2571 (2011)

[24] Mavropoulos E, Costa AM, Costa LT, Achete CA, Mello A, Granjeiro JM, Rossi AM, Colloids Surf. B: Biointerfaces, 83, 1 (2011)

[25] Ghosh S, Goswami SK, Mathias LJ, J. Mater. Chem. A, 1, 6073 (2013)

[26] Ek S, Root A, Peussa M, Niinisto L, Thermochim. Acta, 379(1-2), 201 (2001)

[27] Binks BP, Lumsdon SO, Langmuir, 16(23), 8622 (2000)

[28] Binks BP, Rodrigues JA, Angew. Chem.-Int. Edit., 46, 5389 (2007)

[29] Binks BP, Rodrigues JA, Colloids Surf. A: Physicochem. Eng. Asp., 345, 195 (2009)

[30] Binks BP, Lumsdon SO, Langmuir, 16(8), 3748 (2000)

[31] Zhang J, Li L, Xu J, Sun D, Colloid Polym. Sci., 292, 441 (2014)

[32] Cho WG, J. Soc. Cosmet. Sci. Korea, 36, 1 (2010)

[33] Tambe DE, Sharma MM, J. Colloid Interface Sci., 157, 244 (1993)

[34] Binks BP, Horozov TS, Angew. Chem.-Int. Edit., 117, 3788 (2005)

[35] Rio E, Drenckhan W, Salonen A, Langevin D, Adv. Colloid Interface Sci., 205, 74 (2014)

[36] Fletcher PDI, Holt B, Langmuir, 27(21), 12869 (2011)

[37] Gonzenbach UT, Studart AR, Tervoort E, Gauckler LJ, Angew. Chem.-Int. Edit., 45, 3526 (2006)