화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.74, 223-232, June, 2019
DOI10.1016/j.jiec.2019.03.012  Export Citation
Highly sulfonated polymer-grafted graphene oxide composite membranes for proton exchange membrane fuel cells
Hyunhee Lee, Jusung Han, Kihyun Kim1, Junghwan Kim, Eunki Kim, Huiseob Shin, and Jong-Chan Lee†
  • Department of Chemical and Biological Engineering and Institute of Chemical Processes, Seoul National University, 599 Gwanak-ro, Gwanak-gu, Seoul 151-744, Republic of Korea
  • 1School of Materials Science and Engineering, Polymer Science and Engineering, Gyeongsang National University, 501 Jinju-daero, Jinju 660-701, South Korea
E-mail:
Sulfonated poly(arylene ether sulfone) (SPAES) composite membranes were prepared using graphene oxide (GO) and sulfonated poly(arylene thioether sulfone)-grafted graphene oxide (SATS-GO) as fillers for proton exchange membrane fuel cell (PEMFC) applications. When GO and SATS-GO were mixed with SPAES to form the composite membranes, dimensional stability, chemical stability, and mechanical strength were improved. The composite membranes containing SATS-GO especially showed higher proton conductivity than the pristine SPAES and the composite membrane containing GO because of highly sulfonated polymer (SATS) introduced on GO surface. Furthermore, the sulfonic acid groups in SATS-GO can increase the compatibility between the filler and matrix polymer.
Keywords:Sulfonated poly(arylene ether sulfone);Graphene oxide;Composite membranes;Proton exchange membrane;Fuel cell
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