The construction of uniform nanodots CeO2 stabilized by porous silica matrix (CeO2@SiO2-T) was synthesized by a spontaneous deposition method. Based on the XRD and TEM results, the CeO2 nanodots were highly dispersed on the porous silica matrix. The characterizations including O-2-TPD, XPS, and NH3-TPD clarified that CeO2@SiO2-T catalysts possessed strong acidity, rich surface adsorbed oxygen species and oxygen mobility, which was beneficial to the improvement of adsorption and catalytic oxidation of 1,2-dichloroethane (DCE). The CeO2@SiO2-T catalysts exhibited high performance for DCE oxidation, in which the CeO2@SiO2-400 catalyst showed the best performance (T-90 = 275 degrees C at a space velocity of 15000 h(-1)) and good stability (at 295 degrees C for 100 h). The characterization and activity test results showed that the richer acid sites were beneficial to the adsorption and activation of DCE, contributing to the subsequent HCl removal and vinyl chloride (VC) formation. Noticeably, the weak acid sites were more favorable for the improvement of catalytic activity. Then major of VC would be oxidized to adsorbed acetate, which could be further decomposed to CO(x)and HCl. In addition, trace poly-chlorinated by-products were detected. The abundant surface adsorbed oxygen species and excellent oxygen mobility facilitated the further oxidation rather than the chlorination reactions.