Ethynylferrocene (FcC CH) was utilized as a redox-active metalloligand for the synthesis of polynuclear coinage metal complexes. The reaction of [FcC CLi] with tri-tert-butylphosphine metal chlorides [(Bu3P)-Bu-t-MCl] (M = Au, Ag, Cu) yielded different heteronuclear ferrocene-funtionalized alkyne complexes featuring metallophilic interactions. Furthermore, the redox properties of the ferrocenyl-functionalized tetracopper complex were investigated by cyclic voltammetry and UV-vis-near-IR spectroelectrochemistry. They indicate the compounds' redox-rich nature and a weak electronic coupling between the redox-active ferrocenyl units over a large distance.